Bonds and lone pairs in the flexible coordination sphere of lead(II)

被引：13

作者：

Hall, Annegret K. ^{[1
]}

Harrowfield, Jack M. ^{[1
]}

Morsali, Ali ^{[2
]}

Soudi, Ali A. ^{[2
]}

Yanovsky, Alexander ^{[3
]}

机构：

[1] Univ Western Australia, Special Res Ctr Adv Mineral & Mat Proc, Nedlands, WA 6907, Australia

[2] Univ Zanjan, Dept Chem, Zanjan, Iran

[3] Russian Acad Sci, Xray Struct Ctr, Moscow 117813, Russia

来源：

CRYSTENGCOMM | 2000年 / 13期

关键词：

D O I：

10.1039/b001972k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The single crystal XRD characterisation of a 'mixed anion' complex of Pb(II) with 1,10-phenanthroline, [Pb(phen)(O2CCH3)(O2ClO2)], shows the complex to be polymeric as a result of acetate ligand bridging, the Pb atom being in an unsymmetrical eight-coordinate, N2O6, environment and the crystal array reflecting a strong influence of pi-pi stacking of the heteroaromatic chelate ligands. The structure is used to raise issues concerning the coordination sphere of lead(II) which are of relevance to the rational design of solid state arrays.

引用

页码：82 / 85

页数：4

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