Bonds and lone pairs in the flexible coordination sphere of lead(II)

被引：13

作者：

Hall, Annegret K. ^{[1
]}

Harrowfield, Jack M. ^{[1
]}

Morsali, Ali ^{[2
]}

Soudi, Ali A. ^{[2
]}

Yanovsky, Alexander ^{[3
]}

机构：

[1] Univ Western Australia, Special Res Ctr Adv Mineral & Mat Proc, Nedlands, WA 6907, Australia

[2] Univ Zanjan, Dept Chem, Zanjan, Iran

[3] Russian Acad Sci, Xray Struct Ctr, Moscow 117813, Russia

来源：

CRYSTENGCOMM | 2000年 / 13期

关键词：

D O I：

10.1039/b001972k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The single crystal XRD characterisation of a 'mixed anion' complex of Pb(II) with 1,10-phenanthroline, [Pb(phen)(O2CCH3)(O2ClO2)], shows the complex to be polymeric as a result of acetate ligand bridging, the Pb atom being in an unsymmetrical eight-coordinate, N2O6, environment and the crystal array reflecting a strong influence of pi-pi stacking of the heteroaromatic chelate ligands. The structure is used to raise issues concerning the coordination sphere of lead(II) which are of relevance to the rational design of solid state arrays.

引用

页码：82 / 85

页数：4

共 50 条

[21] Hydration and solvation of lead(II) acetylacetonate and the coordination number of lead(II)
Narbutt, J
SOLVENT EXTRACTION AND ION EXCHANGE, 1999, 17 (05) : 1271 - 1280
[22] Oxidative fluorination of P-H bonds in the coordination sphere of tungsten
Bienewald, F
Huy, NHT
Mathey, F
COMPTES RENDUS DE L ACADEMIE DES SCIENCES SERIE II FASCICULE C-CHIMIE, 1999, 2 (14): : 701 - 704
[23] Influence of the steric effect of flexible isomeric phenylenediacetic acids on the resultant lead(II) coordination polymers
Wu, Yunlong
Zhao, Yanqing
Yang, Guo-Ping
Guo, Yanjun
Wang, Yao-Yu
Shi, Qi-Zhen
JOURNAL OF SOLID STATE CHEMISTRY, 2015, 223 : 131 - 137
[24] Effect of lone pairs on the optical properties of lead oxide materials: Response due to stress
Zwanziger, Josef W.
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2005, 230 : U2240 - U2240
[25] STRUCTURAL STUDY OF LEAD ORTHOPHOSPHOVANADATES - ROLE OF THE ELECTRON LONE PAIRS IN THE PHASE-TRANSITIONS
KIAT, JM
GARNIER, P
CALVARIN, G
PINOT, M
JOURNAL OF SOLID STATE CHEMISTRY, 1993, 103 (02) : 490 - 503
[26] Lead(II) Coordination Sphere and Ligand Coordination Mode Changes During Removal of Water Molecule by Solid-state Thermal Conversion
Moghadam, Zarin
Akhbari, Kamran
Phuruangrat, Anukorn
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2018, 644 (23): : 1641 - 1645
[27] Structural and spectroscopic impact of tuning the stereochemical activity of the lone pair in lead(II) cyanoaurate coordination polymers via ancillary ligands
Katz, Michael J.
Michaelis, Vladimir K.
Aguiar, Pedro M.
Yson, Renante
Lu, Haiyan
Kaluarachchi, Harini
Batchelor, Raymond J.
Schreckenbach, Georg
Kroeker, Scott
Patterson, Howard H.
Leznoff, Daniel B.
INORGANIC CHEMISTRY, 2008, 47 (14) : 6353 - 6363
[28] Bonds, bands, and band gaps in tetrahedrally bonded ternary compounds: The role of group V lone pairs
Do, Dat T.
Mahanti, S. D.
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2014, 75 (04) : 477 - 485
[29] Analysis of Optical Activity in Terms of Bonds and Lone-Pairs: The Exceptionally Large Optical Rotation of Norbornenone
Moore, Barry, II
Srebro, Monika
Autschbach, Jochen
JOURNAL OF CHEMICAL THEORY AND COMPUTATION, 2012, 8 (11) : 4336 - 4346
[30] HEXAMMINE COMPLEXES OF NICKEL(II) WITH MIXED COORDINATION SPHERE
SHEVCHENKO, YN
DAVIDENKO, NK
MANORIK, PA
YATSIMIRSKII, KB
ZHURNAL NEORGANICHESKOI KHIMII, 1977, 22 (02): : 417 - 424

← 1 2 3 4 5 →