Synthesis and structure of a new three-dimentional open-framework zinc phosphate with 12-membered ring channels

被引:0
|
作者
Wang, C [1 ]
Li, J [1 ]
Wang, Y [1 ]
Wang, K [1 ]
Yu, J [1 ]
Xu, R [1 ]
机构
[1] Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130023, Peoples R China
关键词
zinc phosphate; open framework; hydrothermal synthesis; structure;
D O I
暂无
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A new three-dimensional zinc phosphate [Zn6P5O20](3-)center dot[C6N3H15](3+)center dot H2O (I) has been hydrothermally synthesized from a reaction system Zn(OAC)(2)-1-(2-aminoethyl)piperazine-H3PO4-H2O. Single crystal X-ray diffraction analysis shows that it crystallizes in the monoclinic space group C2/c (no. 15) with a=20.240(4), b=16.856(3), c=8.1541(16)angstrom, beta=111.02(3)degrees, V=2596.7(9)angstrom(3) and Z=4. Its structure consists of one dimensional 12-membered ring channels along the [001] direction.
引用
收藏
页码:1035 / 1040
页数:6
相关论文
共 50 条
  • [21] A new open-framework fluorinated gallium phosphate with large 18-ring channels (MIL-31)
    Sassoye, C
    Loiseau, T
    Taulelle, F
    Férey, G
    CHEMICAL COMMUNICATIONS, 2000, (11) : 943 - 944
  • [22] Three-dimensional Open-framework Zinc Phosphite: Synthesis and Characterization
    Chen, Ruixin
    Xu, Lingyan
    Sun, Changfeng
    2011 INTERNATIONAL CONFERENCE ON FUZZY SYSTEMS AND NEURAL COMPUTING (FSNC 2011), VOL III, 2011, : 218 - 220
  • [23] SYNTHESIS AND CRYSTAL-STRUCTURE OF A NOVEL BERYLLIUM PHOSPHATE OPEN-FRAMEWORK STRUCTURE
    HARRISON, WTA
    GIER, TE
    STUCKY, GD
    JOURNAL OF MATERIALS CHEMISTRY, 1991, 1 (01) : 153 - 154
  • [24] Synthesis, characterization and crystal structure analysis of an open-framework zirconium phosphate
    Dong, Jinxiang
    Liu, Lei
    Li, Jinping
    Li, Yi
    Baerlocher, Christian
    McCusker, Lynne B.
    MICROPOROUS AND MESOPOROUS MATERIALS, 2007, 104 (1-3) : 185 - 191
  • [25] Synthesis and characterization of two new open-framework zinc phosphites [M(C6N4H18)][Zn3(HPO3)4] (M = Ni, Co) with multi-directional intersecting 12-membered ring channels
    Liang, J
    Li, JY
    Yu, JH
    Pan, QH
    Fang, QR
    Xu, RR
    JOURNAL OF SOLID STATE CHEMISTRY, 2005, 178 (09) : 2673 - 2679
  • [26] Synthesis and structure of the first open-framework cadmium oxalate possessing channels
    Prasad, PA
    Neeraj, S
    Natarajan, S
    Rao, CNR
    CHEMICAL COMMUNICATIONS, 2000, (14) : 1251 - 1252
  • [28] Synthesis of a new zeolite structure ITQ-24, with intersecting 10-and 12-membered ring pores
    Castañeda, R
    Corma, A
    Fornés, V
    Rey, F
    Rius, J
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (26) : 7820 - 7821
  • [29] Synthesis and characterization of Mu-19, a new zincophosphate with a three-dimensional 12-membered ring channel system
    Simon, A
    Josien, L
    Gramlich, V
    Patarin, J
    MICROPOROUS AND MESOPOROUS MATERIALS, 2001, 47 (2-3) : 135 - 146
  • [30] Synthesis and structure of manganese zinc phosphate-phosphite with extra large twenty-membered ring channels
    Yang, Yang
    Zhao, Yong-Nan
    Yu, Jian-Guo
    Gaodeng Xuexiao Huaxue Xuebao/Chemical Journal of Chinese Universities, 2007, 28 (12): : 2252 - 2254