Synthesis and structure of a new three-dimentional open-framework zinc phosphate with 12-membered ring channels

被引：0
|
作者：
Wang, C [1 ]
Li, J [1 ]
Wang, Y [1 ]
Wang, K [1 ]
Yu, J [1 ]
Xu, R [1 ]
机构：
[1] Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130023, Peoples R China
来源：
RECENT ADVANCES IN THE SCIENCE AND TECHNOLOGY OF ZEOLITES AND RELATED MATERIALS, PTS A - C | 2004年 / 154卷
关键词：
zinc phosphate; open framework; hydrothermal synthesis; structure;
D O I：
暂无
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A new three-dimensional zinc phosphate [Zn6P5O20](3-)center dot[C6N3H15](3+)center dot H2O (I) has been hydrothermally synthesized from a reaction system Zn(OAC)(2)-1-(2-aminoethyl)piperazine-H3PO4-H2O. Single crystal X-ray diffraction analysis shows that it crystallizes in the monoclinic space group C2/c (no. 15) with a=20.240(4), b=16.856(3), c=8.1541(16)angstrom, beta=111.02(3)degrees, V=2596.7(9)angstrom(3) and Z=4. Its structure consists of one dimensional 12-membered ring channels along the [001] direction.
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收藏
页码：1035 / 1040
页数：6
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