Synthesis, spectroscopic characterization, and crystal structures of two chlorodiorganotin(IV) 4-(2-methoxyphenyl)piperazine-1-carbodithioates

被引：24

作者：

Zia-ur-Rehman ^{[1
,2
]}

Barsan, Mirela M. ^{[1
]}

Wharf, Ivor ^{[1
]}

Muhammad, Niaz ^{[2
]}

Ali, Saqib ^{[2
]}

Meetsma, Auke ^{[3
]}

Butler, Ian S. ^{[1
]}

机构：

[1] McGill Univ, Dept Chem, Montreal, PQ H3A 2K6, Canada

[2] Quaid I Azam Univ, Dept Chem, Islamabad 45320, Pakistan

[3] Univ Groningen, Crystal Struct Ctr, Zernike Inst Adv Mat, NL-9747 AG Groningen, Netherlands

来源：

INORGANICA CHIMICA ACTA | 2008年 / 361卷 / 11期

基金：

加拿大自然科学与工程研究理事会;

关键词：

Dithiocarboxylate; Chlorodiorganotin complexes; Raman; NMR; Mass spectra; X-ray diffraction;

D O I：

10.1016/j.ica.2008.05.006

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two chlorodiorganotin(IV) complexes of 4-(2-methoxyphenyl)piperazine-1-carbodithioate (MPPDA) have been synthesized by 1:1 mole-ratio reactions of the parent acid (MPPDAH) with Me2SnCl2 or Et2SnCl2 in dry methanol. The products have been characterized by Raman and multinuclear NMR (H-1, C-13 and Sn-119) spectroscopy, elemental analysis, and mass spectrometry. Single-crystal X-ray diffraction studies indicate that both complexes have distorted trigonal bipyramidal geometries around the central Sn atom. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：3322 / 3326

页数：5

共 50 条

[41] Diethyl 4-(2-methoxyphenyl)-2,6-dimethyl- 1,4-dihydropyridine-3,5-dicarboxylate
Wang, Ke
Wang, Yifeng
Yao, Minjie
Xu, Danqian
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : O785 - +
[42] Synthesis, characterization and antibacterial activity of 3-(2-methoxyphenyl)-2-sulfanylpropenoic acid and di-isopropylammonium [3-(2-methoxyphenyl)-2-sulfanylpropenoato] triphenylstannate(IV).: The crystal structure of [HQ][SnPh3(o-mpspa)]
Alvarez-Boo, Pedro
Casas, Jose S.
Castellano, Eduardo. E.
Couce, M. Deffina
Farto, Rosa
Freijanes, Eduardo
Sordo, Jose
APPLIED ORGANOMETALLIC CHEMISTRY, 2007, 21 (01) : 49 - 53
[43] 1,1′-[4-(2-Methoxyphenyl)-2,6-dimethyl-1,4-dihydropyridine-3,5-diyl]diethanone
Reddy, B. Palakshi
Vijayakumar, V.
Suresh, J.
Narasimhamurthy, T.
Lakshman, P. L. Nilantha
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : O2877 - U1980
[44] 2-[4-(2-Methoxyphenyl)piperazin-1-yl]-N-(pyridin-2-yl)acetamide
Lu, Chunxiong
Jiang, Quanfu
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O223 - U3328
[45] STRUCTURE OF 1-(1-ETHYNYLCYCLOHEXYLOXY)-3-[4-(2-METHOXYPHENYL)-1-PIPERAZINYL] 2-PROPANOL-(RS)
MAIRESSE, G
BOIVIN, JC
THOMAS, DJ
BONTE, JP
LESIEUR, D
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1987, 43 : 2128 - 2130
[46] 5-Aryl Substituted 2-(2-Methoxyphenyl)benzoxazoles with Large Stokes Shifts: Synthesis, Crystal Structures and Optical Properties
Lopez-Marquez, Isai
Lopez-Ruiz, Heraclio
Merino, Gabriel
Vazquez-Garcia, Rosa A.
Corona-Diaz, Alejandro
Perez-Estrada, Salvador
Rojas-Lima, Susana
CHEMPHOTOCHEM, 2024, 8 (06)
[47] Synthesis and crystal structure of 6-(1-benzyl-5-methyl-1H-1,2,3-triazol-4-yl)-4-(2-methoxyphenyl)-3,4-dihydropyrimidine-2(1H)-thione
Murugavel, S.
Lakshmanan, D.
Nagarajan, Sangaraiah
Ponnuswamy, Alagusundaram
BULGARIAN CHEMICAL COMMUNICATIONS, 2015, 47 (01): : 50 - 54
[48] Synthesis, spectroscopic characterization and crystal structures of thorium(IV) mononuclear lactato and hexanuclear formato complexes
Zhang, Yingjie
Karatchevtseva, Inna
Kadi, Fatima
Lu, Kim
Yoon, Bongho
Price, Jason R.
Li, Feng
Lumpkin, Gregory R.
POLYHEDRON, 2015, 87 : 377 - 382
[49] N-{2-[4-(2-Methoxyphenyl)piperazin-1-yl]ethyl}pyridin-2-amine monohydrate
Jiang, Quan-Fu
Lu, Chun-Xiong
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : O1727 - U766
[50] Crystal and molecular structure of N-tert-butyl-3[4-(2-methoxyphenyl)-1-piperazinyl]-2-phenylpropanamide dihydrochloride (WAY-100135)
Fruzinski, A
KarolakWojciechowska, J
Mokrosz, MJ
Bojarski, AJ
POLISH JOURNAL OF CHEMISTRY, 1997, 71 (11) : 1611 - 1617

← 1 2 3 4 5 →