Synthesis, spectroscopic characterization, and crystal structures of two chlorodiorganotin(IV) 4-(2-methoxyphenyl)piperazine-1-carbodithioates

被引：24

作者：

Zia-ur-Rehman ^{[1
,2
]}

Barsan, Mirela M. ^{[1
]}

Wharf, Ivor ^{[1
]}

Muhammad, Niaz ^{[2
]}

Ali, Saqib ^{[2
]}

Meetsma, Auke ^{[3
]}

Butler, Ian S. ^{[1
]}

机构：

[1] McGill Univ, Dept Chem, Montreal, PQ H3A 2K6, Canada

[2] Quaid I Azam Univ, Dept Chem, Islamabad 45320, Pakistan

[3] Univ Groningen, Crystal Struct Ctr, Zernike Inst Adv Mat, NL-9747 AG Groningen, Netherlands

来源：

INORGANICA CHIMICA ACTA | 2008年 / 361卷 / 11期

基金：

加拿大自然科学与工程研究理事会;

关键词：

Dithiocarboxylate; Chlorodiorganotin complexes; Raman; NMR; Mass spectra; X-ray diffraction;

D O I：

10.1016/j.ica.2008.05.006

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two chlorodiorganotin(IV) complexes of 4-(2-methoxyphenyl)piperazine-1-carbodithioate (MPPDA) have been synthesized by 1:1 mole-ratio reactions of the parent acid (MPPDAH) with Me2SnCl2 or Et2SnCl2 in dry methanol. The products have been characterized by Raman and multinuclear NMR (H-1, C-13 and Sn-119) spectroscopy, elemental analysis, and mass spectrometry. Single-crystal X-ray diffraction studies indicate that both complexes have distorted trigonal bipyramidal geometries around the central Sn atom. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：3322 / 3326

页数：5

共 50 条

[21] Synthesis, characterization, single crystal XRD and biological screenings of organotin(IV) derivatives with 4-(2-hydroxyethyl) piperazine-1-carbodithioic acid
Hussain, Shabbir
Ali, Saqib
Shahzadi, Saira
Tahir, Muhammad Nawaz
Shahid, Muhammad
JOURNAL OF COORDINATION CHEMISTRY, 2016, 69 (04) : 687 - 703
[22] Crystal structure of 4-[(2-methoxyphenyl) carbamoyl]butanoic acid, C12H15NO4
Hanifa, Bibi
Sirajuddin, Muhammad
Khan, Hizbullah
Lo, Kong Mun
Tiekink, Edward R. T.
ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2020, 235 (06): : 1481 - 1483
[23] 4-[5-(2-Methoxyphenyl)-1,3,4-oxadiazol-2-yl]benzohydrazide
Taha, Muhammad
Ismail, Nor Hadiani
Imran, Syahrul
Khan, Khalid M.
MOLBANK, 2014, (02)
[24] Crystal structure of trans-1-(2-methoxyphenyl)-4-[4-(2-phthalimido)cyclohexyl]-piperazine chloride monohydrate, (C25H30N3O3)Cl•H2O
Karoak-Wojciechowska, J
Fruzinski, A
Paluchowska, A
Mokrosz, M
ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2002, 217 (03): : 437 - 438
[25] Synthesis of Ethyl 4-Aryl-2-imino-1-(2-methoxyphenyl)-5-[(2-methoxyphenyl)carbamoyl]-6-oxopiperidine-3-carboxylates
Khachatryan, A. Kh.
Avagyan, K. A.
Sargsyan, A. A.
Badasyan, A. E.
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2024, 60 (04) : 743 - 746
[26] Synthesis and crystal structure of {η5:η1-[(2-methoxyphenyl)-isopropyl]-indenyl}(dimethoxyethylene)lithium
Feng, QQ
Li, YM
Wang, SW
Zhou, SL
Sheng, EH
Huang, ZX
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2005, 24 (09) : 1046 - 1048
[27] Organotin(IV) derivatives based on 2-((2-methoxyphenyl)carbamoyl)benzoic acid: Synthesis, spectroscopic characterization, assessment of antibacterial, DNA interaction, anticancer and antileishmanial potentials
Sirajuddin, Muhammad
Ali, Saqib
Tahir, Muhammad Nawaz
JOURNAL OF MOLECULAR STRUCTURE, 2021, 1229
[28] Synthesis, Crystal Structure, Hirshfeld Surface Analysis and Biological Activity of 1-(Bis(4-methoxyphenyl)-methyl)-4-(2-(2-methylphenoxy)ethyl)piperazine
Zhong Yan
Zhu Yi-Jie
Gao Ya-Rong
Xu Yi
Li Ping
Wu Bin
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2019, 38 (07) : 1093 - 1098
[29] Synthesis, Crystal Structure, Hirshfeld Surface Analysis and Biological Activity of 1-(Bis(4-methoxyphenyl)-methyl)-4-(2-(2-methylphenoxy)ethyl)piperazine
仲琰
朱义杰
高雅蓉
许逸
李萍
吴斌
Chinese Journal of Structural Chemistry, 2019, 38 (07) : 1093 - 1098
[30] Synthesis and structural characterization of 1,4-di(2-methoxyphenyl)-2,5-piperazinedione
Zhang Shu-Sheng
Wen Yong-Hong
Tang Xiao-Fang
Li Xue-Mei
CHINESE JOURNAL OF CHEMISTRY, 2007, 25 (05) : 714 - 717

← 1 2 3 4 5 →