Revisiting Sodium Hypochlorite Pentahydrate (NaOCl•5H 2 O) for the Oxidation of Alcohols in Acetonitrile without Nitroxyl Radicals

被引：9
|
作者：
Hirashita, Tsunehisa [1 ]
Sugihara, Yuto [1 ]
Ishikawa, Shota [1 ]
Naito, Yohei [1 ]
Matsukawa, Yuta [1 ]
Araki, Shuki [1 ]
机构：
[1] Nagoya Inst Technol, Grad Sch Engn, Life Sci & Appl Chem, Showa Ku, Gokiso Cho, Nagoya, Aichi 4668555, Japan
来源：
SYNLETT | 2018年 / 29卷 / 18期
关键词：
oxidation; alcohol; sodium hypochlorite pentahydrate; aldehyde; ketone; SELECTIVE OXIDATION; SECONDARY ALCOHOLS; CARBOXYLIC-ACIDS; CONVENIENT; ALDEHYDES; CRYSTALS; OXIDANT; CONVERSION; KETONES; TEMPO;
D O I：
10.1055/s-0037-1609629
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Sodium hypochlorite pentahydrate (NaOCl center dot 5H(2)O) is capable of oxidizing alcohols in acetonitrile at 20 degrees C without the use of catalysts. The oxidation is selective to allylic, benzylic, and secondary alcohols. Aliphatic primary alcohols are not oxidized.
引用
收藏
页码：2404 / 2407
页数：4
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