A synergistic effect in the combination of H2O2, FeAPO-5 and NaBr for selective oxidation of benzyl alcohols

被引：13
|
作者：
Qi, Lin [1 ]
Qi, Xingyi [1 ]
Wang, Jing [1 ]
Zheng, Liwei [1 ]
机构：
[1] Beihang Univ, Sch Chem & Environm, Key Lab Bioinspired Smart Interfacial Sci & Techn, Minist Educ, Beijing 100191, Peoples R China
来源：
CATALYSIS COMMUNICATIONS | 2011年 / 16卷 / 01期
关键词：
Selective oxidation; Benzyl alcohols; Hydrogen peroxide; FeAPO-5 molecular sieves; Sodium bromide; ALUMINOPHOSPHATE MOLECULAR-SIEVES; LIQUID-PHASE OXIDATION; CATALYTIC-PROPERTIES; AEROBIC OXIDATION; ORGANIC-COMPOUNDS; ALDEHYDES; BROMINE;
D O I：
10.1016/j.catcom.2011.09.035
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The H2O2/FeAPO-5/NaBr combination has been found to be active in the oxidation of benzyl alcohols. The remarkably different activity results obtained with the H2O2/FeAPO-5/NaBr, the H2O2/FeAPO-5 and the H2O2/NaBr confirm the existence of a strongly synergistic effect in the ternary reaction system of H2O2. FeAPO-5 and NaBr, leading to a significantly enhanced conversion of benzyl alcohols under mild reaction conditions. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码：225 / 228
页数：4
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