Revisiting Sodium Hypochlorite Pentahydrate (NaOCl•5H 2 O) for the Oxidation of Alcohols in Acetonitrile without Nitroxyl Radicals

被引：9

作者：

Hirashita, Tsunehisa ^{[1
]}

Sugihara, Yuto ^{[1
]}

Ishikawa, Shota ^{[1
]}

Naito, Yohei ^{[1
]}

Matsukawa, Yuta ^{[1
]}

Araki, Shuki ^{[1
]}

机构：

[1] Nagoya Inst Technol, Grad Sch Engn, Life Sci & Appl Chem, Showa Ku, Gokiso Cho, Nagoya, Aichi 4668555, Japan

来源：

SYNLETT | 2018年 / 29卷 / 18期

关键词：

oxidation; alcohol; sodium hypochlorite pentahydrate; aldehyde; ketone; SELECTIVE OXIDATION; SECONDARY ALCOHOLS; CARBOXYLIC-ACIDS; CONVENIENT; ALDEHYDES; CRYSTALS; OXIDANT; CONVERSION; KETONES; TEMPO;

D O I：

10.1055/s-0037-1609629

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Sodium hypochlorite pentahydrate (NaOCl center dot 5H(2)O) is capable of oxidizing alcohols in acetonitrile at 20 degrees C without the use of catalysts. The oxidation is selective to allylic, benzylic, and secondary alcohols. Aliphatic primary alcohols are not oxidized.

引用

页码：2404 / 2407

页数：4

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