Crystal structure and mesogenic property of an iron(II) complex with a terpyridine derivative ligand

被引：13

作者：

Hayami, S

Danjobara, K

Shigeyoshi, Y

Inoue, K

Ogawa, Y

Maeda, Y

机构：

[1] Kyushu Univ, Grad Sch Sci, Dept Chem, Higashi Ku, Fukuoka 8128581, Japan

[2] Hiroshima Univ, Fac Sci, Dept Chem, Higashihiroshima 7398526, Japan

[3] Kumamoto Univ, Fac Sci, Dept Chem, Kumamoto 8608555, Japan

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2005年 / 8卷 / 06期

关键词：

metallomesogen; iron(II) complex;

D O I：

10.1016/j.inoche.2005.03.002

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Iron(II) compound [Fe(C16-terpy)(2)](BF4)(2) (1) was synthesized, and exhibited liquid crystal transition. The thermodynamically stable form of the compound I is a low-spin state at room temperature. The single crystal X-ray analysis revealed the structure for iron(II) compound [Fe(C-16-terpy)(2)](ClO4)(2) center dot acetone (1'). It can be understood that the low-spin iron(II) compound I is new type metallomesogen. (C) 2005 Elsevier B.V. All rights reserved.

引用

页码：506 / 509

页数：4

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