Synthesis and Crystal Structure of an Iron(II) Complex With Nitronyl Nitroxides

被引：2

作者：

Wang, Xiaoling ^{[1
]}

Wen, Guilin ^{[1
]}

Wang, Fengwu ^{[1
]}

Chen, Yonghong ^{[1
]}

Zhao, Xing ^{[1
]}

Bao, Xia ^{[1
]}

机构：

[1] Huainan Normal Univ, Dept Chem & Chem Engn, Anhui Key Lab Low Temp Cofired Mat, Huainan 232001, Peoples R China

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2016年 / 46卷 / 02期

基金：

美国国家科学基金会;

关键词：

nitronyl nitroxide radical; Fe(II) complex; crystal structure; SPIN-CROSSOVER; ORGANIC FERROMAGNET; MAGNETIC-PROPERTIES; FREE-RADICALS; SYSTEM; IMINO;

D O I：

10.1080/15533174.2014.963242

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An iron(II) complex with nitronyl nitroxides, [Fe-II(NIT4Py)(2)(N(CN)(2))(2)(H2O)(2)] (NIT4Py = 2-(4-pyridyl)- 4,4,5,5-tetramethylimidazoline-1-oxyl 3-oxide), was synthesized and characterized by X-ray diffraction analysis, elemental analyses, and IR spectrum. X-ray analysis reveals that the center Fe(II) ion is six-coordinated with a slightly distorted octahedral geometry. The adjacent monomeric entities are linked by hydrogen bonds to generate a 3D structure.

引用

页码：206 / 209

页数：4

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