Synthesis and Crystal Structure of an Iron(II) Complex With Nitronyl Nitroxides

被引：2
|
作者：
Wang, Xiaoling [1 ]
Wen, Guilin [1 ]
Wang, Fengwu [1 ]
Chen, Yonghong [1 ]
Zhao, Xing [1 ]
Bao, Xia [1 ]
机构：
[1] Huainan Normal Univ, Dept Chem & Chem Engn, Anhui Key Lab Low Temp Cofired Mat, Huainan 232001, Peoples R China
来源：
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2016年 / 46卷 / 02期
基金：
美国国家科学基金会;
关键词：
nitronyl nitroxide radical; Fe(II) complex; crystal structure; SPIN-CROSSOVER; ORGANIC FERROMAGNET; MAGNETIC-PROPERTIES; FREE-RADICALS; SYSTEM; IMINO;
D O I：
10.1080/15533174.2014.963242
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
An iron(II) complex with nitronyl nitroxides, [Fe-II(NIT4Py)(2)(N(CN)(2))(2)(H2O)(2)] (NIT4Py = 2-(4-pyridyl)- 4,4,5,5-tetramethylimidazoline-1-oxyl 3-oxide), was synthesized and characterized by X-ray diffraction analysis, elemental analyses, and IR spectrum. X-ray analysis reveals that the center Fe(II) ion is six-coordinated with a slightly distorted octahedral geometry. The adjacent monomeric entities are linked by hydrogen bonds to generate a 3D structure.
引用
收藏
页码：206 / 209
页数：4
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