Crystal structure and mesogenic property of an iron(II) complex with a terpyridine derivative ligand

被引：13
|
作者：
Hayami, S
Danjobara, K
Shigeyoshi, Y
Inoue, K
Ogawa, Y
Maeda, Y
机构：
[1] Kyushu Univ, Grad Sch Sci, Dept Chem, Higashi Ku, Fukuoka 8128581, Japan
[2] Hiroshima Univ, Fac Sci, Dept Chem, Higashihiroshima 7398526, Japan
[3] Kumamoto Univ, Fac Sci, Dept Chem, Kumamoto 8608555, Japan
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2005年 / 8卷 / 06期
关键词：
metallomesogen; iron(II) complex;
D O I：
10.1016/j.inoche.2005.03.002
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Iron(II) compound [Fe(C16-terpy)(2)](BF4)(2) (1) was synthesized, and exhibited liquid crystal transition. The thermodynamically stable form of the compound I is a low-spin state at room temperature. The single crystal X-ray analysis revealed the structure for iron(II) compound [Fe(C-16-terpy)(2)](ClO4)(2) center dot acetone (1'). It can be understood that the low-spin iron(II) compound I is new type metallomesogen. (C) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码：506 / 509
页数：4
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