H3PW12O40 catalyzed liquid phase nitration of aromatics - a green process without using H2SO4

被引：0
|
作者：
Lu, Lianhai [1 ,2 ]
Xin, Junna [1 ]
Woo, Chang-Soo [2 ]
Cai, Tianxi [1 ]
Lee, Ho-In [2 ]
机构：
[1] Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116012, Peoples R China
[2] Seoul Natl Univ, Sch Chem & Biol Engn, Energy Res Ctr Convers & Storage, Seoul 151, South Korea
来源：
NEW DEVELOPMENT AND APPLICATION IN CHEMICAL REACTION ENGINEERING, 4TH ASIA-PACIFIC CHEMICAL REACTION ENGINEERING SYMPOSIUM (APCRE 05) | 2006年 / 159卷
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D O I：
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中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
H3PW12O40 with Keggin structure showed excellent activity for liquid phase nitration of various aromatic compounds, suggesting the possibility of a green nitration process by simply replacing H2SO4 in current nitration unit. The H3PW12O40 could be recycled to use with constant activity. Effects of various reaction parameters were investigated extensively.
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页码：353 / 356
页数：4
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