H3PW12O40 catalyzed liquid phase nitration of aromatics - a green process without using H2SO4

被引：0
|
作者：
Lu, Lianhai [1 ,2 ]
Xin, Junna [1 ]
Woo, Chang-Soo [2 ]
Cai, Tianxi [1 ]
Lee, Ho-In [2 ]
机构：
[1] Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116012, Peoples R China
[2] Seoul Natl Univ, Sch Chem & Biol Engn, Energy Res Ctr Convers & Storage, Seoul 151, South Korea
来源：
NEW DEVELOPMENT AND APPLICATION IN CHEMICAL REACTION ENGINEERING, 4TH ASIA-PACIFIC CHEMICAL REACTION ENGINEERING SYMPOSIUM (APCRE 05) | 2006年 / 159卷
关键词：
D O I：
暂无
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
H3PW12O40 with Keggin structure showed excellent activity for liquid phase nitration of various aromatic compounds, suggesting the possibility of a green nitration process by simply replacing H2SO4 in current nitration unit. The H3PW12O40 could be recycled to use with constant activity. Effects of various reaction parameters were investigated extensively.
引用
收藏
页码：353 / 356
页数：4
相关论文
共 50 条
  • [31] Repeated use of supported H3PW12O40 catalysts in the liquid phase esterification of acetic acid with butanol
    Sepúlveda, JH
    Yori, JC
    Vera, CR
    APPLIED CATALYSIS A-GENERAL, 2005, 288 (1-2) : 18 - 24
  • [32] Tungstophosphoric acid (H3PW12O40) catalyzed oxidation of organic compounds with NaBrO3
    Shaabani, Ahmad
    Behnam, Maryam
    Rezayan, Ali Hossein
    CATALYSIS COMMUNICATIONS, 2009, 10 (07) : 1074 - 1078
  • [33] Comparison of H3PW12O40 and H4SiW12O40 heteropolyacids supported on silica by 1H MAS NMR
    Thomas, A
    Dablemont, C
    Basset, JM
    Lefebvre, F
    COMPTES RENDUS CHIMIE, 2005, 8 (11-12) : 1969 - 1974
  • [34] The mechanism of the selective NOx sorption on H3PW12O40•6H2O (HPW)
    Hodjati, S
    Vaezzadeh, K
    Petit, C
    Pitchon, V
    Kiennemann, A
    TOPICS IN CATALYSIS, 2001, 16 (1-4) : 151 - 155
  • [35] Photocatalysis of H3PW12O40 for 4-chlorophenol decomposition in aqueous media
    Einaga, H
    Misono, M
    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1996, 69 (12) : 3435 - 3441
  • [36] The Mechanism of the Selective NOx Sorption on H3PW12O40·6H2O (HPW)
    S. Hodjati
    K. Vaezzadeh
    C. Petit
    V. Pitchon
    A. Kiennemann
    Topics in Catalysis, 2001, 16-17 : 151 - 155
  • [37] EFFECT OF HEATING METHOD ON NOx DECOMPOSITION ON H3PW12O40•6H2O
    Zhang, Xueyang
    Cheng, Lin
    Wang, Rui
    BULLETIN OF THE CHEMICAL SOCIETY OF ETHIOPIA, 2013, 27 (02) : 281 - 287
  • [38] Catalytic synthesis of acetals and ketals with H3PW12O40/PAn
    Yang Shuijin
    Mang Yijun
    Du Xinxian
    Merle, Philippe G.
    RARE METALS, 2008, 27 (01) : 89 - 94
  • [39] An acidity scale for Bronsted acids including H3PW12O40
    Drago, RS
    Dias, JA
    Maier, TO
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (33) : 7702 - 7710
  • [40] Catalytic synthesis of acetals and ketals with H3PW12O40/PAn
    Philippe G.Merleb
    RareMetals, 2008, (01) : 89 - 94
12345