Copper-mediated ortho C-H sulfonylation of benzoic acid derivatives with sodium sulfinates

被引：102
|
作者：
Liu, Jidan [1 ]
Yu, Lin [1 ]
Zhuang, Shaobo [1 ]
Gui, Qingwen [1 ]
Chen, Xiang [1 ]
Wang, Wenduo [1 ]
Tan, Ze [1 ]
机构：
[1] Hunan Univ, Coll Chem & Chem Engn, State Key Lab Chemo Biosensing & Chemometr, Changsha 410082, Hunan, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 29期
基金：
中国国家自然科学基金;
关键词：
UNSYMMETRICAL DIARYL SULFONES; EFFICIENT METHOD; BOND FORMATION; ARYL; ARENES; AMIDATION; SALTS; ALKYNYLATION; INHIBITORS; C(SP(3))-H;
D O I：
10.1039/c5cc00202h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Copper-mediated direct ortho C-H bond sulfonylation of benzoic acid derivatives with sodium sulfinates was achieved by employing an 8-aminoquinoline moiety as the bidentate directing group. Various aryl sulfones were synthesized in good yields with excellent regioselectivity.
引用
收藏
页码：6418 / 6421
页数：4
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