Copper-mediated C-H bond arylation of arenes with arylboronic acids

被引：140
|
作者：
Ban, Ikuya [1 ]
Sudo, Tomoko [1 ]
Taniguchi, Tadashi
Itami, Kenichiro [1 ,2 ]
机构：
[1] Nagoya Univ, Grad Sch Sci, Dept Chem, Nagoya, Aichi 4648602, Japan
[2] Japan Sci & Technol Agcy, PRESTO, Kanagawa, Japan
来源：
ORGANIC LETTERS | 2008年 / 10卷 / 16期
关键词：
D O I：
10.1021/ol8013717
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A new copper-mediated cross-coupling of arenes and arylboronic acids is described. Under the influence of Cu(OCOCF3)(2), the C-H bond arylation of electron-rich arenes with arylboronic acids takes place to afford a range of biaryis in good yields. The reaction is selective for cross-coupling; no homocoupling product arising from arenes or arylboronic acids is detected. Multiple C-H bond arylation is possible with indoles and pyrroles furnishing interesting extended pi-systems.
引用
收藏
页码：3607 / 3609
页数：3
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