Copper-mediated ortho C-H sulfonylation of benzoic acid derivatives with sodium sulfinates

被引：102
|
作者：
Liu, Jidan [1 ]
Yu, Lin [1 ]
Zhuang, Shaobo [1 ]
Gui, Qingwen [1 ]
Chen, Xiang [1 ]
Wang, Wenduo [1 ]
Tan, Ze [1 ]
机构：
[1] Hunan Univ, Coll Chem & Chem Engn, State Key Lab Chemo Biosensing & Chemometr, Changsha 410082, Hunan, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 29期
基金：
中国国家自然科学基金;
关键词：
UNSYMMETRICAL DIARYL SULFONES; EFFICIENT METHOD; BOND FORMATION; ARYL; ARENES; AMIDATION; SALTS; ALKYNYLATION; INHIBITORS; C(SP(3))-H;
D O I：
10.1039/c5cc00202h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Copper-mediated direct ortho C-H bond sulfonylation of benzoic acid derivatives with sodium sulfinates was achieved by employing an 8-aminoquinoline moiety as the bidentate directing group. Various aryl sulfones were synthesized in good yields with excellent regioselectivity.
引用
收藏
页码：6418 / 6421
页数：4
相关论文
共 50 条
  • [31] Synthesis of Sulfonylated Lactams by Copper-Mediated Aminosulfonylation of 2-Vinylbenzamides with Sodium Sulfinates
    Wang, Li-Jing
    Chen, Jia-Min
    Dong, Wei
    Hou, Cong-Ying
    Pang, Mingming
    Jin, Wen-Bo
    Dong, Fu-Gui
    Xu, Zhi-Dong
    Li, Wei
    JOURNAL OF ORGANIC CHEMISTRY, 2019, 84 (04): : 2330 - 2338
  • [32] Copper-Mediated Enantioselective C-H Thiolation of Ferrocenes Enabled by the BINOL Ligand
    Ma, Jia-Yi
    Yao, Qi-Jun
    Jiang, Lu-Chen
    Huang, Fan-Rui
    Yue, Qiang
    Shi, Bing-Feng
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2025, 147 (08) : 7061 - 7069
  • [33] Copper-mediated stereospecific C-H oxidative sulfenylation of terminal alkenes with disulfides
    Tu, Hai-Yong
    Hu, Bo-Lun
    Deng, Chen-Liang
    Zhang, Xing-Guo
    CHEMICAL COMMUNICATIONS, 2015, 51 (85) : 15558 - 15561
  • [34] Electrochemical Oxidative C(sp3)-H Sulfonylation of Xanthenes with Sodium Sulfinates
    Wei Bin
    Zhou Zilong
    Qin Jinghao
    Yan Zeyu
    Guo Jiacheng
    Lei Shu
    Xie Yexiang
    Ouyang Xuanhui
    Song Renjie
    CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2023, 43 (01) : 186 - 194
  • [35] Copper-Mediated ortho-C-H Amination Using DMF as the Amine Source
    Cheng, Tai-Jin
    Chen, Jun-Jie
    Wu, Peng
    Xu, Hui
    Dai, Hui-Xiong
    ORGANIC LETTERS, 2021, 23 (21) : 8505 - 8509
  • [36] Copper-Mediated ortho-Arylation of Benzamides with Arylboronic Acid
    Gui, Qingwen
    Chen, Xiang
    Hu, Liang
    Wang, Dadian
    Liu, Jidan
    Tan, Ze
    ADVANCED SYNTHESIS & CATALYSIS, 2016, 358 (04) : 509 - 514
  • [37] Copper-Mediated ortho-Nitration of Arene and Heteroarene C-H Bonds Assisted by an 8-Aminoquinoline Directing Group
    Liu, Jidan
    Zhuang, Shaobo
    Gui, Qingwen
    Chen, Xiang
    Yang, Zhiyong
    Tan, Ze
    ADVANCED SYNTHESIS & CATALYSIS, 2015, 357 (04) : 732 - 738
  • [38] Copper mediated decarboxylative direct C-H arylation of heteroarenes with benzoic acids
    Patra, Tuhin
    Nandi, Sudip
    Sahoo, Santosh K.
    Maiti, Debabrata
    CHEMICAL COMMUNICATIONS, 2016, 52 (07) : 1432 - 1435
  • [39] Copper-mediated oxidative C-H/N-H activations with alkynes by removable hydrazides
    Xiong, Feng
    Li, Bo
    Yang, Chenrui
    Zou, Liang
    Ma, Wenbo
    Gu, Linghui
    Mei, Ruhuai
    Ackermann, Lutz
    BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, 2021, 17 : 1591 - 1599
  • [40] Copper-mediated C-H amination of 2H-indazoles with N-Fluorobenzenesulfonimide
    Li, Zhenhua
    Ye, Lixian
    Cao, Yingyan
    Qin, Jinjing
    Wang, Wenbiao
    Xie, Yuanyuan
    TETRAHEDRON LETTERS, 2021, 83
12345