Copper-mediated ortho C-H sulfonylation of benzoic acid derivatives with sodium sulfinates

被引：102
|
作者：
Liu, Jidan [1 ]
Yu, Lin [1 ]
Zhuang, Shaobo [1 ]
Gui, Qingwen [1 ]
Chen, Xiang [1 ]
Wang, Wenduo [1 ]
Tan, Ze [1 ]
机构：
[1] Hunan Univ, Coll Chem & Chem Engn, State Key Lab Chemo Biosensing & Chemometr, Changsha 410082, Hunan, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 29期
基金：
中国国家自然科学基金;
关键词：
UNSYMMETRICAL DIARYL SULFONES; EFFICIENT METHOD; BOND FORMATION; ARYL; ARENES; AMIDATION; SALTS; ALKYNYLATION; INHIBITORS; C(SP(3))-H;
D O I：
10.1039/c5cc00202h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Copper-mediated direct ortho C-H bond sulfonylation of benzoic acid derivatives with sodium sulfinates was achieved by employing an 8-aminoquinoline moiety as the bidentate directing group. Various aryl sulfones were synthesized in good yields with excellent regioselectivity.
引用
收藏
页码：6418 / 6421
页数：4
相关论文
共 50 条
  • [1] Copper-Mediated Decarboxylative Sulfonylation of Arylacetic Acids with Sodium Sulfinates
    Wu, Yinrong
    Chen, Jiewen
    Li, Lu
    Wen, Kangmei
    Yao, Xingang
    Pang, Jianxin
    Wu, Ting
    Tang, Xiaodong
    ORGANIC LETTERS, 2020, 22 (18) : 7164 - 7168
  • [2] Copper-Mediated Sulfonylation of Aryl C(sp2)-H Bonds with Sodium and Lithium Sulfinates
    Liang, Shuai
    Liu, Nai-Wei
    Manolikakes, Georg
    ADVANCED SYNTHESIS & CATALYSIS, 2016, 358 (01) : 159 - 163
  • [3] Copper-Mediated C-H/C-H Biaryl Coupling of Benzoic Acid Derivatives and 1,3-Azoles
    Nishino, Mayuko
    Hirano, Koji
    Satoh, Tetsuya
    Miura, Masahiro
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (16) : 4457 - 4461
  • [4] Copper-mediated ortho C-H primary amination of anilines
    Cheng, Tai-Jin
    Wang, Xing
    Xu, Hui
    Dai, Hui-Xiong
    TETRAHEDRON LETTERS, 2021, 73
  • [5] Copper-Catalyzed Direct C-H Bond Oxidative Sulfonylation of β-Alkyl Cyanoalkenes with Sodium Sulfinates
    Jin, Junyi
    Zhou, Kaiyang
    Liu, Xinxiang
    Wang, Can
    Chen, Yunfeng
    ASIAN JOURNAL OF ORGANIC CHEMISTRY, 2023, 12 (08)
  • [6] Manganese(III) Acetate Mediated C-H Sulfonylation of 1,4-Dimethoxybenzenes with Sodium and Lithium Sulfinates
    Liang, Shuai
    Ren, Yueling
    Manolikakes, Georg
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2017, 2017 (28) : 4117 - 4120
  • [7] Copper-mediated C-H(sp2)/C-H(sp3) coupling of benzoic acid derivatives with ethyl cyanoacetate: an expedient route to an isoquinolinone scaffold
    Zhu, Wei
    Zhang, Dengyou
    Yang, Nan
    Liu, Hong
    CHEMICAL COMMUNICATIONS, 2014, 50 (73) : 10634 - 10636
  • [8] Direct C(sp3)-H Sulfonylation of Xanthene Derivatives with Sodium Sulfinates by Oxidative Copper Catalysis
    Song, Qinghao
    Zhao, He
    Sun, Yanping
    Jiang, Huanfeng
    Zhang, Min
    CHINESE JOURNAL OF CHEMISTRY, 2022, 40 (03): : 371 - 377
  • [9] Copper-mediated C-H trifluoromethylation of quinones
    Ilchenko, Nadia O.
    Janson, Par G.
    Szabo, Kalman J.
    CHEMICAL COMMUNICATIONS, 2013, 49 (59) : 6614 - 6616
  • [10] Copper-mediated selective oxidation of a C-H bond
    Boldron, C
    Gamez, P
    Tooke, DM
    Spek, AL
    Reedijk, J
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (23) : 3585 - 3587
12345