Synthesis and Characterisation of Schiff Base-like Iron(II) Complexes with Imidazole as Axial Ligand

被引：9

作者：

Lochenie, Charles ^{[1
]}

Bauer, Wolfgang ^{[1
]}

Schlamp, Stephan ^{[1
]}

Thoma, Peter ^{[1
]}

Weber, Birgit ^{[1
]}

机构：

[1] Univ Bayreuth, D-95440 Bayreuth, Germany

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2012年 / 638卷 / 01期

关键词：

Iron; Magnetic properties; X-ray Structure; Spin crossover; Hydrogen bonds; SPIN-CROSSOVER COMPLEXES; MAGNETIC-PROPERTIES;

D O I：

10.1002/zaac.201100424

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Four new six-coordinate and one pentacoordinate iron(II) complexes with imidazole as axial ligand were synthesised and characterised. For two of the complexes crystals suitable for X-ray structure analysis were obtained and an extended network of hydrogen bonds was observed in both cases. Magnetic susceptibility studies revealed, that two of the octahedral complexes are high-spin complexes in the entire temperature range, whereas for the other two gradual spin transitions are observed.

引用

页码：98 / 102

页数：5

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