Synthesis and Characterisation of Schiff Base-like Iron(II) Complexes with Imidazole as Axial Ligand

被引：9
|
作者：
Lochenie, Charles [1 ]
Bauer, Wolfgang [1 ]
Schlamp, Stephan [1 ]
Thoma, Peter [1 ]
Weber, Birgit [1 ]
机构：
[1] Univ Bayreuth, D-95440 Bayreuth, Germany
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2012年 / 638卷 / 01期
关键词：
Iron; Magnetic properties; X-ray Structure; Spin crossover; Hydrogen bonds; SPIN-CROSSOVER COMPLEXES; MAGNETIC-PROPERTIES;
D O I：
10.1002/zaac.201100424
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Four new six-coordinate and one pentacoordinate iron(II) complexes with imidazole as axial ligand were synthesised and characterised. For two of the complexes crystals suitable for X-ray structure analysis were obtained and an extended network of hydrogen bonds was observed in both cases. Magnetic susceptibility studies revealed, that two of the octahedral complexes are high-spin complexes in the entire temperature range, whereas for the other two gradual spin transitions are observed.
引用
收藏
页码：98 / 102
页数：5
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