New Pincer-Type Platinum (II) Complexes with 1,3-bis((diphenyl)phosphinoxy)phenyl Ligand. Synthesis, Structure and Electrochemical Properties

被引：1
|
作者：
Verpekin, Victor V. [1 ]
Chudin, Oleg S. [1 ]
Burmakina, Galina, V [1 ]
Kondrasenko, Alexander A. [1 ]
Zimonin, Dmitry, V [1 ,2 ]
Peterson, Ivan, V [1 ]
机构：
[1] Krasnoyarsk Sci Ctr SB RAS, Fed Res Ctr, Inst Chem & Chem Technol SB RAS, Krasnoyarsk, Russia
[2] Siberian Fed Univ, Krasnoyarsk, Russia
来源：
JOURNAL OF SIBERIAN FEDERAL UNIVERSITY-CHEMISTRY | 2022年 / 15卷 / 02期
关键词：
platinum; pincer ligands; alkynyl ligands; benzothiadiazole; electrochemistry; ALKYNYL COMPLEXES; METALS;
D O I：
10.17516/1998-2836-0290
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The reactions of 1,3-bis((diphenyl)phosphinoxy)benzene and PtCl2(L)(2) (L = SMe2, OSMe2, C5H5N) gave the new pincer-type 1,3-bis((diphenyl)phosphinoxy)phenyl platinum (II) complex [eta 3-kappa P:kappa C:kappa P-C6H3-1,3-(OPPh2)(2)]PtCl (1). The reaction between compound 1 and 4-ethynl-2,1,3benzothiadiazole in the presence of copper iodide lead to the new complex [C6H3-1,3-(OPPh2)(2)]Pt-CC(4-C6H3N2S) (2) containing a terminal (4-benzothiadiazol-2,1,3-yDethynyl ligand. The compounds were characterized by IR- and NMR-spectroscopy. These spectroscopy data allow us to propose the molecular structures of 1 and 2. The electrochemical properties of the new complexes were studied, the outcomes of their redox-reactions were proposed.
引用
收藏
页码：251 / 264
页数：14
相关论文
共 50 条
  • [41] Cadmium coordination compounds with flexible ligand 1,3-bis(1,2,4-triazol-1-yl)propane: Synthesis, structure and luminescent properties
    Smirnova, Ksenia S.
    Lider, Elizaveta, V
    Sukhikh, Taisiya S.
    Berezin, Alexey S.
    Potapov, Andrei S.
    POLYHEDRON, 2020, 177
  • [42] Palladium(II) complexes bearing the new pincer ligand 3,5-bis(indazol-2-ylmethyl)toluene; synthesis and catalytic properties
    Hurtado, John
    Ibanez, Andres
    Rojas, Rene
    Valderrama, Mauricio
    INORGANIC CHEMISTRY COMMUNICATIONS, 2010, 13 (09) : 1025 - 1028
  • [43] Synthesis and structural characterization of Cu(I) and that Ni(II) complexes that contain the bis[2-(diphenylphosphino)phenyl]ether ligand. Novel emission properties for the Cu(I) species
    Kuang, SM
    Cuttell, DG
    McMillin, DR
    Fanwick, PE
    Walton, RA
    INORGANIC CHEMISTRY, 2002, 41 (12) : 3313 - 3322
  • [44] Copper(II) and cobalt(II) complexes based on bis-benzimidazolyl ligand with 1,2-bis(2′-ethoxy)phenyl linker: synthesis, crystal structure and conformations
    Liu, Qing-Xiang
    Bi, Yue
    Zhao, Xiao-Jun
    Zhao, Zhi-Xiang
    Wang, Jian-Hua
    Wang, Xiu-Guang
    CRYSTENGCOMM, 2014, 16 (10): : 1950 - 1962
  • [45] Synthesis, Crystal Structure and Spectra Properties of the Nickel (II) Complex with 1,3-bis(1-benzylbenzimidazol2-yl)-2-Oxopropane
    Wu, Huilu
    Yun, Ruirui
    Li, Ke
    Wang, Kaitong
    Huang, Xingcai
    Sun, Tao
    SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2009, 39 (09) : 614 - 617
  • [46] Synthesis, Crystal Structure, and Spectra Properties of the Cadmium(II) Complex With 1,3-bis(1-ethylbenzimidazol-2-yl)-2-oxopropane
    Wu, Huilu
    Kou, Fan
    Liu, Bin
    Jia, Fei
    Yuan, Jingkun
    Bai, Ying
    Yun, Ruirui
    Fan, Xuyang
    SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2012, 42 (06) : 839 - 842
  • [47] Dinuclear ruthenium(II) and/or osmium(II) complexes of a non-symmetric bis-chelating quaterpyridine ligand. Synthesis, electrochemical behaviour, absorption spectra, luminescence properties and intercomponent energy transfer
    J Chem Soc Dalton Trans, (3601):
  • [48] Synthesis, electrochemical and spectroscopic properties of ruthenium(II) complexes containing 1,3-bis([1,10]phenanthroline-[5,6-d]imidazol-2-yl)benzene
    Chao, H
    Ye, BH
    Li, H
    Li, RH
    Zhou, JY
    Ji, LN
    POLYHEDRON, 2000, 19 (16-17) : 1975 - 1983
  • [49] Synthesis and crystal structures of silver(I), palladium(II), zinc(II) and cobalt(II) complexes of the ditoptic ligand 1,3-bis(imidazol-1-ylmethyl)-2,4,6-trimethylbenzene
    Liu, HK
    Hu, J
    Wang, TW
    Yu, XL
    Liu, J
    Kang, BS
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2001, (23): : 3534 - 3540
  • [50] Synthesis of metallacarborane ruthenium(II) and ruthenium(III) complexes with chelate 1,3-bis(diphenylphosphino)propane ligand and their mutual transformation in one-electron redox reactions
    Grishin, I. D.
    Agafonova, K. S.
    Kostyukovich, A. Yu.
    D'yachihin, D. I.
    Godovikov, I. A.
    Dolgushin, F. M.
    Grishin, D. F.
    Chizhevsky, I. T.
    RUSSIAN CHEMICAL BULLETIN, 2016, 65 (06) : 1574 - 1579
12345