New Pincer-Type Platinum (II) Complexes with 1,3-bis((diphenyl)phosphinoxy)phenyl Ligand. Synthesis, Structure and Electrochemical Properties

被引：1
|
作者：
Verpekin, Victor V. [1 ]
Chudin, Oleg S. [1 ]
Burmakina, Galina, V [1 ]
Kondrasenko, Alexander A. [1 ]
Zimonin, Dmitry, V [1 ,2 ]
Peterson, Ivan, V [1 ]
机构：
[1] Krasnoyarsk Sci Ctr SB RAS, Fed Res Ctr, Inst Chem & Chem Technol SB RAS, Krasnoyarsk, Russia
[2] Siberian Fed Univ, Krasnoyarsk, Russia
来源：
JOURNAL OF SIBERIAN FEDERAL UNIVERSITY-CHEMISTRY | 2022年 / 15卷 / 02期
关键词：
platinum; pincer ligands; alkynyl ligands; benzothiadiazole; electrochemistry; ALKYNYL COMPLEXES; METALS;
D O I：
10.17516/1998-2836-0290
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The reactions of 1,3-bis((diphenyl)phosphinoxy)benzene and PtCl2(L)(2) (L = SMe2, OSMe2, C5H5N) gave the new pincer-type 1,3-bis((diphenyl)phosphinoxy)phenyl platinum (II) complex [eta 3-kappa P:kappa C:kappa P-C6H3-1,3-(OPPh2)(2)]PtCl (1). The reaction between compound 1 and 4-ethynl-2,1,3benzothiadiazole in the presence of copper iodide lead to the new complex [C6H3-1,3-(OPPh2)(2)]Pt-CC(4-C6H3N2S) (2) containing a terminal (4-benzothiadiazol-2,1,3-yDethynyl ligand. The compounds were characterized by IR- and NMR-spectroscopy. These spectroscopy data allow us to propose the molecular structures of 1 and 2. The electrochemical properties of the new complexes were studied, the outcomes of their redox-reactions were proposed.
引用
收藏
页码：251 / 264
页数：14
相关论文
共 50 条
  • [31] Phosphorescent Square-Planar Platinum(II) Complexes of 1,3-Bis(2-pyridylimino)isoindoline with a Monodentate Strong-Field Ligand
    Wen, Hu-Min
    Wang, Jin-Yun
    Li, Bin
    Zhang, Li-Yi
    Chen, Chang-Neng
    Chen, Zhong-Ning
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2013, 2013 (27) : 4789 - 4798
  • [32] Complexes of the 1,3-bis(2-arylimino)benz(f) isoindoline ligand including the crystal structure of the Cu(II) acetate complex
    Baird, DM
    Maehlmann, WP
    Bereman, RD
    Singh, P
    JOURNAL OF COORDINATION CHEMISTRY, 1997, 42 (1-2) : 107 - 126
  • [33] SYNTHESIS AND CRYSTAL-STRUCTURE OF NEW SIGMA-BONDED ALKYNYLCOBALT(III) COMPLEXES OF 1,3-BIS(DIACETYLMONOXIMEIMINO)PROPANE
    GIESE, B
    ZEHNDER, M
    NEUBURGER, M
    TRACH, F
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 412 (03) : 415 - 423
  • [34] SYNTHESIS AND STRUCTURE OF NEW Er(III) COMPLEXES WITH N,N′-1,3-BIS(2,6-DIISOPROPYLPHENYL)TRIAZENIDE
    Kolybalov, D. S.
    Sukhikh, T. S.
    Bashirov, D. A.
    Konchenko, S. N.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2021, 62 (02) : 277 - 284
  • [35] SYNTHESIS AND STRUCTURE OF NEW Er(III) COMPLEXES WITH N,N′-1,3-BIS(2,6-DIISOPROPYLPHENYL)TRIAZENIDE
    D. S. Kolybalov
    T. S. Sukhikh
    D. A. Bashirov
    S. N. Konchenko
    Journal of Structural Chemistry, 2021, 62 : 277 - 284
  • [36] Synthesis, spectroscopic and electrochemical studies on bis-[1,3-substituted (Cl, Br) phenyl-5-phenyl formazanato]nickel(II) complexes
    Tezcan, Habibe
    Uzluk, Elif
    Aksu, M. Levent
    SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2008, 70 (05) : 973 - 982
  • [37] MAGNETIC-PROPERTIES AND CRYSTAL-STRUCTURE OF BINUCLEAR COPPER(II) COMPLEXES WITH 1,3-BIS(HYDROXYMETHYL)-2-IMIDAZOLIDINETHIONE
    TOKII, T
    NAKASHIMA, M
    FURUKAWA, T
    MUTO, Y
    LINTVEDT, RL
    CHEMISTRY LETTERS, 1990, (03) : 363 - 366
  • [38] The first Ru(η3-PCP) complexes of the electron-rich pincer ligand 1,3-bis((dicyclohexylphosphino)methyl)benzene:: Structure and mechanism in transfer hydrogenation catalysis
    Amoroso, D
    Jabri, A
    Yap, GPA
    Gusev, DG
    dos Santos, EN
    Fogg, DE
    ORGANOMETALLICS, 2004, 23 (17) : 4047 - 4054
  • [39] Synthesis, Crystal Structure and Electrochemical Properties of the Copper() Complex with 1,3-bis(benzimidazol-2-yl)-2-oxopropane
    Wu, Huilu
    Yun, Ruirui
    Wang, Kaitong
    Huang, Xingcai
    Sun, Tao
    Li, Ke
    SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2009, 39 (07) : 406 - 409
  • [40] V-shaped ligand 1,3-bis(1-ethylbenzimidazol-2-yl)-2-thiapropane and manganese(II), cobalt(II) and copper(II) complexes: Synthesis, crystal structure, DNA-binding properties and antioxidant activities
    Wu, Huilu
    Yang, Zaihui
    Wang, Fei
    Peng, Hongping
    Zhang, Han
    Wang, Cuiping
    Wang, Kaitong
    JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY B-BIOLOGY, 2015, 148 : 252 - 261
12345