Recent progress in transition-metal-catalyzed hydrocyanation of nonpolar alkenes and alkynes

被引：30
|
作者：
Zhang, Hongru [1 ]
Su, Xin [1 ]
Dong, Kaiwu [1 ]
机构：
[1] East China Normal Univ, Chang Kung Chuang Inst, Shanghai Key Lab Green Chem & Chem Proc, Sch Chem & Mol Engn, Shanghai 200062, Peoples R China
来源：
ORGANIC & BIOMOLECULAR CHEMISTRY | 2020年 / 18卷 / 03期
关键词：
PHOSPHINE-PHOSPHITE LIGANDS; STEREOSELECTIVE HYDROCYANATION; REGIOSELECTIVE HYDROCYANATION; ORGANOMETALLIC COMPOUNDS; TRIMETHYLSILYL CYANIDE; HYDROGEN-CYANIDE; NICKEL; STEREOCHEMISTRY; ALLENES; INTERCONVERSION;
D O I：
10.1039/c9ob02374g
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Hydrocyanation is a powerful method for the preparation of nitriles which are versatile building blocks for the synthesis of amines, acids and amides. This review summarizes the research on transition-metal-catalyzed (asymmetric) hydrocyanation of nonpolar (or non-activated) alkenes and alkynes in the last decade. These studies involve the extension of HCN surrogates and unsaturated substrates, catalyst development as well as the improvement of the activity and multiple selectivities. The remaining challenges and personal future perspectives are presented at the end.
引用
收藏
页码：391 / 399
页数：9
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