Transition-metal-catalyzed domino reactions of strained bicyclic alkenes

被引：9
|
作者：
Pounder, Austin [1 ]
Neufeld, Eric [1 ]
Myler, Peter [1 ]
Tam, William [1 ]
机构：
[1] Univ Guelph, Guelph Waterloo Ctr Grad Work Chem & Biochem, Dept Chem, Guelph, ON N1G 2W1, Canada
来源：
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY | 2023年 / 19卷
基金：
加拿大自然科学与工程研究理事会;
关键词：
bicyclic alkenes; cascade; catalysis; domino; transition-metal-catalyzed; C-H ACTIVATION; 3-COMPONENT COUPLING REACTION; ONE-POT STRATEGY; SPIROTRICYCLIC OLEFINS; DIAZABICYCLIC OLEFINS; OXABICYCLIC ALKENES; EFFICIENT SYNTHESIS; 2+2 CYCLOADDITIONS; NICKEL-COMPLEXES; CASCADE REACTION;
D O I：
10.3762/bjoc.19.38
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
This review presents a comprehensive overview of transition-metal-catalyzed domino reactions of strained bicyclic alkenes, including both homo- and heterobicyclic alkenes. These compounds are important synthons in organic synthesis, providing an important platform for the construction of biologically/medicinally significant compounds which bear multiple stereocenters. The review has been divided according to the metal used in the reaction. An overview of the substrate scope, reaction conditions, and their potential applications in organic synthesis is discussed. A comprehensive outlook on the reactivity paradigms of homo- and heterobicyclic alkenes is discussed and should shed light on future directions for further development in this field.
引用
收藏
页码：487 / 540
页数：54
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