Photoinduced reactions of tertiary amines with [60]fullerene; Addition of an alpha-C-H bond of amines to [60]fullerene

被引：65

作者：

Liou, KF ^{[1
]}

Cheng, CH ^{[1
]}

机构：

[1] NATL TSING HUA UNIV,DEPT CHEM,HSINCHU 300,TAIWAN

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 12期

关键词：

D O I：

10.1039/cc9960001423

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The photochemical reaction of [60]fullerene with RNMe(2) (R = Ph and Me) gives an adduct (1, R = Ph; 2, R = Me) formed by the addition of an alpha-C-H bond of the amine to a 6/6 ring junction of [60]fullerene; 2 on further irradiation in the presence of [60]fullerene is converted to the pyrrolidine derivative 3 and 1,2-H2C60.

引用

页码：1423 / 1424

页数：2

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