Functionalization of [60]Fullerene via Palladium-Catalyzed C-H Bond Activation

被引：40
|
作者：
Wang, Guan-Wu [1 ,2 ]
机构：
[1] Univ Sci & Technol China, Natl Lab Phys Sci Microscale, CAS Key Lab Soft Matter Chem, iChEM Collaborat Innovat Ctr Chem Energy Mat, Hefei 230026, Anhui, Peoples R China
[2] Univ Sci & Technol China, Dept Chem, Hefei 230026, Anhui, Peoples R China
来源：
C-H BOND ACTIVATION AND CATALYTIC FUNCTIONALIZATION I | 2016年 / 55卷
关键词：
60]Fullerene; Annulation; Carbocycle; C-H activation; Heterocycle; Palladium catalyst; DECARBOXYLATIVE ORTHO-ACYLATION; PD(II)-CATALYZED AMINATION; ANILIDES; HETEROANNULATION; TETRAALLYLATION; CONSTRUCTION; SULFONAMIDES; ALKOXYLATION; DERIVATIVES; FULLERENE;
D O I：
10.1007/3418_2015_128
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The palladium-catalyzed C-H bond activation strategy has been successfully applied to fullerene chemistry, and several types of [60] fullerene-fused heterocycles and carbocycles have been obtained. The synthesis of [60] fullerene-fused indolines, isoquinolinones, azepines, tetrahydroisoquinolines, tetrahydrobenzazepines, sultones, tetrahydrobenzooxepines/isochromans, and dihydrophenanthrenes has been achieved by the palladium-catalyzed reactions of [60] fullerene with anilides, benzamides, N-sulfonyl-2-aminobiaryls, N-benzyl sulfonamides, N-(2-arylethyl) sulfonamides, arylsulfonic acids, 2-phenylethyl/benzyl alcohols, and 2-arylbenzoic acids, respectively.
引用
收藏
页码：119 / 136
页数：18
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