Functionalization of [60]Fullerene via Palladium-Catalyzed C-H Bond Activation

被引：40
|
作者：
Wang, Guan-Wu [1 ,2 ]
机构：
[1] Univ Sci & Technol China, Natl Lab Phys Sci Microscale, CAS Key Lab Soft Matter Chem, iChEM Collaborat Innovat Ctr Chem Energy Mat, Hefei 230026, Anhui, Peoples R China
[2] Univ Sci & Technol China, Dept Chem, Hefei 230026, Anhui, Peoples R China
来源：
C-H BOND ACTIVATION AND CATALYTIC FUNCTIONALIZATION I | 2016年 / 55卷
关键词：
60]Fullerene; Annulation; Carbocycle; C-H activation; Heterocycle; Palladium catalyst; DECARBOXYLATIVE ORTHO-ACYLATION; PD(II)-CATALYZED AMINATION; ANILIDES; HETEROANNULATION; TETRAALLYLATION; CONSTRUCTION; SULFONAMIDES; ALKOXYLATION; DERIVATIVES; FULLERENE;
D O I：
10.1007/3418_2015_128
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The palladium-catalyzed C-H bond activation strategy has been successfully applied to fullerene chemistry, and several types of [60] fullerene-fused heterocycles and carbocycles have been obtained. The synthesis of [60] fullerene-fused indolines, isoquinolinones, azepines, tetrahydroisoquinolines, tetrahydrobenzazepines, sultones, tetrahydrobenzooxepines/isochromans, and dihydrophenanthrenes has been achieved by the palladium-catalyzed reactions of [60] fullerene with anilides, benzamides, N-sulfonyl-2-aminobiaryls, N-benzyl sulfonamides, N-(2-arylethyl) sulfonamides, arylsulfonic acids, 2-phenylethyl/benzyl alcohols, and 2-arylbenzoic acids, respectively.
引用
收藏
页码：119 / 136
页数：18
相关论文
共 50 条
  • [41] Dearomatization of Indoles via Palladium-Catalyzed Allylic C-H Activation
    Zhang, Heng
    Hu, Rong-Bin
    Liu, Na
    Li, Shi-Xia
    Yang, Shang-Dong
    ORGANIC LETTERS, 2016, 18 (01) : 28 - 31
  • [42] Palladium-catalyzed method for the synthesis of carbazoles via tandem C-H functionalization and C-N bond formation
    Tsang, W. C. Peter
    Munday, Rachel H.
    Brasche, Gordon
    Zheng, Nan
    Buchwald, Stephen L.
    JOURNAL OF ORGANIC CHEMISTRY, 2008, 73 (19): : 7603 - 7610
  • [43] Palladium-Catalyzed Asymmetric Synthesis of Silicon-Stereogenic Dibenzosiloles via Enantioselective C-H Bond Functionalization
    Shintani, Ryo
    Otomo, Haruka
    Ota, Kensuke
    Hayashi, Tamio
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (17) : 7305 - 7308
  • [44] Synthesis of Ferrocene Derivatives with Planar Chirality via Palladium-Catalyzed Enantioselective C-H Bond Activation
    Pi, Chao
    Cui, Xiuling
    Liu, Xiuyan
    Guo, Mengxing
    Zhang, Hanyu
    Wu, Yangjie
    ORGANIC LETTERS, 2014, 16 (19) : 5164 - 5167
  • [45] Remote C-H Functionalization by a Palladium-Catalyzed Transannular Approach
    De Sarkar, Suman
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2016, 55 (36) : 10558 - 10560
  • [46] Palladium-Catalyzed Directed para C-H Functionalization of Phenols
    Patra, Tuhin
    Bag, Sukdev
    Kancherla, Rajesh
    Mondal, Anirban
    Dey, Aniruddha
    Pimparkar, Sandeep
    Agasti, Soumitra
    Modak, Atanu
    Maiti, Debabrata
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2016, 55 (27) : 7751 - 7755
  • [47] Direct C-3-Alkenylation of Quinolones via Palladium-Catalyzed C-H Functionalization
    Li, Mingzong
    Li, Liangxi
    Ge, Haibo
    ADVANCED SYNTHESIS & CATALYSIS, 2010, 352 (14-15) : 2445 - 2449
  • [48] Synthesis of substituted oxindoles from α-chloroacetanilides via palladium-catalyzed C-H functionalization
    Hennessy, EJ
    Buchwald, SL
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (40) : 12084 - 12085
  • [49] A convergent synthesis of polysubstituted aromatic nitriles via palladium-catalyzed C-H functionalization
    Mariampillai, Brian
    Alliot, Julien
    Li, Mengzhou
    Lautens, Mark
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (49) : 15372 - 15379
  • [50] Palladium-catalyzed direct asymmetric C-H bond functionalization enabled by the directing group strategy
    Yang, Ke
    Song, Mengjie
    Liu, Hao
    Ge, Haibo
    CHEMICAL SCIENCE, 2020, 11 (47) : 12616 - 12632
12345