Photoinduced reactions of tertiary amines with [60]fullerene; Addition of an alpha-C-H bond of amines to [60]fullerene

被引：65
|
作者：
Liou, KF [1 ]
Cheng, CH [1 ]
机构：
[1] NATL TSING HUA UNIV,DEPT CHEM,HSINCHU 300,TAIWAN
来源：
CHEMICAL COMMUNICATIONS | 1996年 / 12期
关键词：
D O I：
10.1039/cc9960001423
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The photochemical reaction of [60]fullerene with RNMe(2) (R = Ph and Me) gives an adduct (1, R = Ph; 2, R = Me) formed by the addition of an alpha-C-H bond of the amine to a 6/6 ring junction of [60]fullerene; 2 on further irradiation in the presence of [60]fullerene is converted to the pyrrolidine derivative 3 and 1,2-H2C60.
引用
收藏
页码：1423 / 1424
页数：2
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