Synthesis and structure of hexaaquacobalt bis(2-methyl-1H-imidazol-3-ium) tetraaquabis(benzene-1,3,5-tricarboxylato-κO)cobalt

被引：0
|
作者：
Velazquez-Garcia, Jose de Jesus [1 ]
Techert, Simone [1 ,2 ]
机构：
[1] DESY, Notkestr 85, D-22607 Hamburg, Germany
[2] Georg August Univ Gottingen, Inst Rontgenphys, Friedrich Hund Pl 1, D-37077 Gottingen, Germany
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2022年 / 78卷
关键词：
crystal structure; hexaaqua-cobalt; 2-methylimidazole; 1,3,5-benzene tricarboxylic acid; GRAPH-SET ANALYSIS; TRANSITION; COMPLEXES; PATTERNS;
D O I：
10.1107/S2056989022007046
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound, (C4H7N2)(2)[Co(H2O)(6)][Co(C9H3O6)(2)(H2O)(4)] (1), was synthesized from cobalt(II) chloride, 1,3,5-benzene tricarboxylic acid (Hbtc) and 2-methyl-imidazole (H-2mIm) under ambient conditions. The structure of 1 is here reported and compared with the parent complex hexaaquacobalt bis(1H-imidazol-3-ium) tetraaquabis(benzene-1,3,5-tricarboxylato)cobalt (2).
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页码：814 / +
页数：10
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