2,4-Bis[(3-butylimidazol-3-ium-1-yl)methyl]-1,3,5-trimethylbenzene bis(hexafluorophosphate)

被引：1
|
作者：
Haque, Rosenani A. [2 ]
Salman, Abbas Washeel [2 ]
Hemamalini, Madhukar [1 ]
Fun, Hoong-Kun [1 ]
机构：
[1] Univ Sains Malaysia, Sch Phys, Xray Crystallog Unit, Usm 11800, Penang, Malaysia
[2] Univ Sains Malaysia, Sch Chem Sci, Usm 11800, Penang, Malaysia
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷
关键词：
N-HETEROCYCLIC CARBENES; COMPLEXES;
D O I：
10.1107/S1600536811003916
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title molecular salt, C25H38N42+center dot 2PF(6)(-), one of the butyl groups and four F atoms in the basal plane of one of the PF6- octahedra are disordered over two sets of sites, with occupancy ratios of 0.704 (5):0.296 (5) and 0.71 (3):0.29 (3), respectively. The central benzene ring makes dihedral angles of 85.17 (12) and 81.97 (12)degrees with the terminal imidazole rings. In the crystal, cations and anions are linked together via intermolecular C-H center dot center dot center dot F hydrogen bonds forming a three-dimensional network.
引用
收藏
页码：O562 / U1221
页数：15
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