Synthesis and structure of hexaaquacobalt bis(2-methyl-1H-imidazol-3-ium) tetraaquabis(benzene-1,3,5-tricarboxylato-κO)cobalt

被引：0
|
作者：
Velazquez-Garcia, Jose de Jesus [1 ]
Techert, Simone [1 ,2 ]
机构：
[1] DESY, Notkestr 85, D-22607 Hamburg, Germany
[2] Georg August Univ Gottingen, Inst Rontgenphys, Friedrich Hund Pl 1, D-37077 Gottingen, Germany
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2022年 / 78卷
关键词：
crystal structure; hexaaqua-cobalt; 2-methylimidazole; 1,3,5-benzene tricarboxylic acid; GRAPH-SET ANALYSIS; TRANSITION; COMPLEXES; PATTERNS;
D O I：
10.1107/S2056989022007046
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound, (C4H7N2)(2)[Co(H2O)(6)][Co(C9H3O6)(2)(H2O)(4)] (1), was synthesized from cobalt(II) chloride, 1,3,5-benzene tricarboxylic acid (Hbtc) and 2-methyl-imidazole (H-2mIm) under ambient conditions. The structure of 1 is here reported and compared with the parent complex hexaaquacobalt bis(1H-imidazol-3-ium) tetraaquabis(benzene-1,3,5-tricarboxylato)cobalt (2).
引用
收藏
页码：814 / +
页数：10
相关论文
共 50 条
  • [41] Crystal structure of 1,1′-butanebis(3-methyl-1H-imidazol-3-ium)bis(hexafluorophosphate), C12H20F12N4P2
    Xiong Wan-Ming
    Jing, Chen
    Peng Da-Yong
    Nie Xu-Liang
    Huang, Chang-gan
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2017, 232 (06): : 1007 - 1008
  • [42] Benzene-1,3,5-tricarboxylic acid-5-(pyridin-1-ium-3-yl)-5H-1,2,3,4-tetrazol-5-ide (1/1)
    Meng, Gao-Xiang
    Ding, Hao
    Feng, Ya-Min
    Zhu, Jian-Hui
    Yang, He-Lin
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O1620 - U2311
  • [43] The crystal structure of 1,4-bis(1H-imidazol-3-ium-1-yl)benzene dinitrate, C12H12N42+<middle dot>2(NO3-)
    An, Hangyi
    Wang, Xiaoli
    Wang, Airong
    Shi, Zhongfeng
    Li, Jiaming
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2024, 239 (04): : 783 - 786
  • [44] Crystal structure of 3,3′-(1,2-phenylenebis (rnethylene))bis(1-methyl-1H-imidazol-3-ium) bis (hexafluoridophosphate), C16H20F12N4P2
    Zhou Yao-Hong
    Huang Ting
    Nie Xu-Liang
    Chen Jing
    Xiong Wan-Ming
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2020, 235 (05): : 1217 - 1219
  • [45] 1-(6-bromopyridin-2-yl)-3-methyl-3H-imidazol-1-ium bromide monohydrate
    Cheng, PY
    Zeng, JY
    Chiu, PL
    Lee, HM
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 : O509 - O510
  • [46] Crystal structure of 3,5-dicarboxybenzoate benzene-1,3,5-tricarboxylic acid (1/1), C24H22N2O12
    Li, Sa-Ying
    Li, Ping
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2016, 231 (02): : 525 - 528
  • [47] Bis(2-propyl-1H-imidazol-3-ium) bis(pyridine-2,6-dicarboxylato-κ3O2,N,O6)cadmate(II)
    Dong, Gui-Ying
    Liu, Tong-Fei
    He, Cui-Hong
    Deng, Xiao-Chen
    Shi, Xiao-Ge
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : M1007 - U1712
  • [48] SYNTHESIS OF 1,3,5-TRIS[(2-METHYLAZIRIDINYL-1)METHYL]BENZENE
    KISHORE, K
    VERNEKER, VRP
    DHARUMARAJ, GV
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1984, 29 (03): : 369 - 369
  • [49] Poly[[(mu(4)-benzene-1,3,5-tricarboxylato kappa O-4(1):O-1 ':O-2:O-3)bis(2,2-bipyridine kappa N-2,N ')(mu(2)-hydroxido)dicopper(II)]trihydrate]
    El-Kaheli, Mohamed N.
    El-Mehdawi, Ramadan M.
    Abuhmaiera, Ramadan G.
    Ben Younes, Mufida M.
    Treish, Fathia A.
    Guerri, Annalisa
    Bazzicalupi, Carla
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2014, 70 : M270 - +
  • [50] Polymeric diaqua(μ2-2,2′-bipyrimidinyl-κ 4N1,N1′:N3,N3′)-di-μ3-hydroxy-bis(μ5-benzene-1,3,5-tricarboxylato-κ5O1 :O2:O3:O3:O5)tetracobalt(II) dihydrate
    Plater, MJ
    Foreman, MRS
    Howie, RA
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 2002, 58 : M487 - M489
12345