Dichlorido[2,4-dimethyl-N-(pyridin-2-ylmethylidene)aniline-κ2 N,N′]dimethyltin(IV)

被引:1
|
作者
Loni, Sedigheh [2 ]
Olyai, Mohamad Reza Talei Bavil [1 ]
Roodbari, Fatemeh [2 ]
Notash, Behrouz [3 ]
机构
[1] Islamic Azad Univ, Dept Chem, S Tehran Branch, Tehran, Iran
[2] Islamic Azad Univ, Dept Chem, Karaj Branch, Karaj, Iran
[3] Shahid Beheshti Univ, GC, Dept Chem, Tehran 1983963113, Iran
关键词
SCHIFF-BASE; MANNICH-BASES; COMPLEXES; ANTIBACTERIAL; ANTIFUNGAL; CRYSTAL;
D O I
10.1107/S1600536811010439
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The asymmetric unit of the title compound, [Sn(CH3)(2)Cl-2(C14H14N2)], contains two crystallographically independent molecules. In each molecule, the SnIV atom is six-coordinated in a distorted octahedral geometry by one bidentate 2,4-dimethyl-N-(pyridin-2-ylmethylidene)aniline ligand, two methyl groups and two Cl atoms. In the crystal, intermolecular C-H...Cl hydrogen bonds link the molecules. There are pi-pi contacts between the pyridine rings of the ligands [centroid-centroid distance = 3.761 (4) A].
引用
收藏
页码:M489 / U938
页数:15
相关论文
共 50 条
  • [31] Crystal structure of dichlorido(2-(1-methyl-1H-benzo[d]imidazol-2-yl) aniline-κ2N,N′)zinc(II)
    Zhou, Ting-Ting
    Zhang, Dong-Mei
    Li, Jia-Wen
    Zhang, Fan
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2016, 231 (02): : 477 - 478
  • [32] Dichlorido(N,N′-diisopropylpiperidine-1-carboximidamidato-κ2N,N′)titanium(IV)
    Wang, Mei
    Yao, Ying-Ming
    Zhang, Yong
    Zhang, Zhen-Qin
    Shi, Li-Ying
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : M125 - U1269
  • [33] N,N′-Dimethyl-N,N′-bis(pyridin-2-yl)methanediamine
    Lee, Moon-Sun
    Yoon, Minyoung
    Yang, O-bong
    Lee, Dong-Heon
    Park, Gyungse
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O3226 - U828
  • [34] Crystal structure of dichlorido[N-(pyridin-2-ylmethyl)aniline]zinc(II), C12H12Cl2N2Zn
    Xu, Hua-Jie
    Sheng, Liang-Quan
    Chen, Ming-Ming
    Liu, Zhao-Di
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2013, 228 (03): : 399 - 400
  • [35] Coordination compounds of cobalt, nickel, copper, and zinc with N1,N2-bis(pyridin-2-ylmethylidene)benzene-1,2-diamine and its derivatives
    E. Pahontu
    A. P. Gulea
    D. Poirier
    V. I. Tsapkov
    Russian Journal of General Chemistry, 2014, 84 : 1767 - 1770
  • [36] Dichlorido{N′-[(pyridin-2-yl)methylidene-κN]acetohydrazide-κ2N′,O}copper(II)
    Datta, Amitabha
    Sheu, Shiann-Cherng
    Liu, Pei-Hsin
    Huang, Jui-Hsien
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : M1852 - U1232
  • [37] Dichlorido{N,N-dimethyl-N′-[1-(pyridin-2-yl)ethylidene]ethane-1,2-diamine-κ3N,N′,N"}cadmium
    Gwaram, Nura Suleiman
    Khaledi, Hamid
    Ali, Hapipah Mohd
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : M348 - U642
  • [38] 2-(2,4-Dihydroxyphenyl)-N,N-dimethyl-2-oxoacetamide
    Huang, W
    Zhao, PL
    Zhou, ZZ
    Chen, Q
    Teng, DY
    Yang, GF
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 : O1505 - O1506
  • [39] Dichlorido-[N,N′-bis(2,6-dimethyl-phenyl)pentane-2,4-diiminato](indenyl)zirconium(IV) toluene hemisolvate
    Verguet, Emilie
    Fortune, Rose-Verla
    Oguadinma, Paul O.
    Schaper, Frank
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2007, 63 : M2539 - U931
  • [40] ORGANOTIN COMPOUNDS WITH 2,2'-BIIMIDAZOLE DERIVATIVES - THE CRYSTAL-STRUCTURE OF DIBROMO(N,N'-DIMETHYL-2,2'-BIIMIDAZOLE)DIMETHYLTIN(IV)
    LOPEZ, C
    GONZALEZ, AS
    GARCIA, ME
    CASAS, JS
    SORDO, J
    GRAZIANI, R
    CASELLATO, U
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1992, 434 (03) : 261 - 268