Dichlorido[2,4-dimethyl-N-(pyridin-2-ylmethylidene)aniline-κ2 N,N′]dimethyltin(IV)

被引:1
|
作者
Loni, Sedigheh [2 ]
Olyai, Mohamad Reza Talei Bavil [1 ]
Roodbari, Fatemeh [2 ]
Notash, Behrouz [3 ]
机构
[1] Islamic Azad Univ, Dept Chem, S Tehran Branch, Tehran, Iran
[2] Islamic Azad Univ, Dept Chem, Karaj Branch, Karaj, Iran
[3] Shahid Beheshti Univ, GC, Dept Chem, Tehran 1983963113, Iran
关键词
SCHIFF-BASE; MANNICH-BASES; COMPLEXES; ANTIBACTERIAL; ANTIFUNGAL; CRYSTAL;
D O I
10.1107/S1600536811010439
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The asymmetric unit of the title compound, [Sn(CH3)(2)Cl-2(C14H14N2)], contains two crystallographically independent molecules. In each molecule, the SnIV atom is six-coordinated in a distorted octahedral geometry by one bidentate 2,4-dimethyl-N-(pyridin-2-ylmethylidene)aniline ligand, two methyl groups and two Cl atoms. In the crystal, intermolecular C-H...Cl hydrogen bonds link the molecules. There are pi-pi contacts between the pyridine rings of the ligands [centroid-centroid distance = 3.761 (4) A].
引用
收藏
页码:M489 / U938
页数:15
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