Dichlorido-[N,N′-bis(2,6-dimethyl-phenyl)pentane-2,4-diiminato](indenyl)zirconium(IV) toluene hemisolvate

被引：6

作者：

Verguet, Emilie ^{[1
]}

Fortune, Rose-Verla ^{[1
]}

Oguadinma, Paul O. ^{[1
]}

Schaper, Frank ^{[1
]}

机构：

[1] Univ Montreal, Dept Chim, Montreal, PQ H3C 3J7, Canada

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2007年 / 63卷

关键词：

D O I：

10.1107/S1600536807043966

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, [Zr(Cl)2(C21H25N2)(C9H7)]·0.5C7H8, [bis-(2,6-dimethyl-phen-yl)nacnac](inden-yl)ZrCl2, where nacnac is the pentane-2,4-diiminate ligand, has pseudo-tetra-hedral coordination geometry about the Zr center. The coordination mode of the nacnac ligand is inter-mediate between k2- and k5-coordination, with both N atoms and two C atoms clearly coordinated to the Zr center. The coordination is best described as an in-plane k1-imine and k3-enaminato coordination of the nacnac ligand. A toluene solvent mol-ecule is present and is disordered about a twofold crystallographic axis. © International Union of Crystallography 2007.

引用

页码：M2539 / U931

页数：17

共 20 条

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