Synthesis of bisabolane sesquiterpenes: A Johnson-Claisen rearrangement approach

被引：7

作者：

Du, Zhen Ting ^{[1
]}

Yu, Hong Rui ^{[1
]}

Xu, Yan ^{[1
]}

Li, Yong ^{[1
]}

Li, An Pai ^{[2
]}

机构：

[1] NW A&F Univ, Coll Sci, Yangling 712100, Peoples R China

[2] Synthet Technol Pte Ltd, Singapore 048693, Singapore

来源：

CHINESE CHEMICAL LETTERS | 2010年 / 21卷 / 07期

基金：

中国国家自然科学基金;

关键词：

Bisabolane sesquiterpenes; Johnson-Claisen rearrangement; Synthesis; ENANTIOSELECTIVE SYNTHESIS; ETHER; (+/-)-CURCUPHENOL; (+)-CURCUPHENOL; TERPENOIDS;

D O I：

10.1016/j.cclet.2010.02.024

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Several bisabolane sesquiterpenes, (+/-)-curcumene, (+/-)-curcuphenol, (+/-)-curcudiol and (+/-)-curcuhydroquinone, have been synthesized in racemic form and fully characterized. The salient characteristic of our approach is that a Johnson-Claisen arrangement was involved as a key step. (C) 2010 Zhen Ting Du. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.

引用

页码：813 / 815

页数：3

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