Synthesis of bisabolane sesquiterpenes: A Johnson-Claisen rearrangement approach

被引：7
|
作者：
Du, Zhen Ting [1 ]
Yu, Hong Rui [1 ]
Xu, Yan [1 ]
Li, Yong [1 ]
Li, An Pai [2 ]
机构：
[1] NW A&F Univ, Coll Sci, Yangling 712100, Peoples R China
[2] Synthet Technol Pte Ltd, Singapore 048693, Singapore
来源：
CHINESE CHEMICAL LETTERS | 2010年 / 21卷 / 07期
基金：
中国国家自然科学基金;
关键词：
Bisabolane sesquiterpenes; Johnson-Claisen rearrangement; Synthesis; ENANTIOSELECTIVE SYNTHESIS; ETHER; (+/-)-CURCUPHENOL; (+)-CURCUPHENOL; TERPENOIDS;
D O I：
10.1016/j.cclet.2010.02.024
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Several bisabolane sesquiterpenes, (+/-)-curcumene, (+/-)-curcuphenol, (+/-)-curcudiol and (+/-)-curcuhydroquinone, have been synthesized in racemic form and fully characterized. The salient characteristic of our approach is that a Johnson-Claisen arrangement was involved as a key step. (C) 2010 Zhen Ting Du. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.
引用
收藏
页码：813 / 815
页数：3
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