Synthesis and Crystal Structure of a New Cd(II) Coordination Polymer Based on Phthalic Acid and bis(imidazole)

被引：0
|
作者：
Gao, Ronghua [1 ]
机构：
[1] Weihai Vocat Coll, Dept Biol & Chem Engn, Weihai 264210, Shandong, Peoples R China
来源：
ASIAN JOURNAL OF CHEMISTRY | 2012年 / 24卷 / 06期
关键词：
Coordination polymer; Crystal structure;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
One new coordination polymer [Cd-2(PAA)(2)(bib)](n) (H(2)PAA= phthalic acid and bib= 4,4'-bis (2-methylimidazol-1-ylmethyl)biphenyl) has been synthesized by the hydrothermal method and characterized by X-ray single crystal diffraction. In compound [Cd-2(PAA)(2)(bib)](n), the phthalic acid ligand acts as bridging ligands exhibiting two coordination modes to link metal ions: bis-monodentate and bidentate chelating/bridging modes. The carboxylic groups bridge Cd(II) ions to an infinite 1D framework. The 4,4'-bis (2-methylimidazol-1-ylmethyl)biphenyl) ligands coordinate to two Cd(II) centers to give rise to a two-dimensional net.
引用
收藏
页码：2823 / 2824
页数：2
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