Formation of 1-D Polymer in Recrystallization of the Adduct Mn[(OOCC5H4)Mn(CO)3]2[O(H)Me]4 from Acetonitrile

被引:0
|
作者
Grineva, A. A. [1 ]
Ageshina, A. A. [1 ]
Uvarova, M. A. [1 ]
Nefedov, S. E. [1 ]
机构
[1] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Leninskii Pr 65, Moscow 119991, Russia
基金
俄罗斯基础研究基金会;
关键词
SINGLE-MOLECULE MAGNETS; MANGANESE(II); METHANOL; DESIGN;
D O I
10.1134/S0036023616090060
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
It was found that the recrystallization of the adduct Mn[(OOCC5H4)Mn(CO)(3)](2)[O(H)Me](4) from hot acetonitrile in the presence of benzene produces polymer {Mn[mu-(OOCC5H4)Mn(CO)(3)](4)[mu-eta(2)-(OOCC5H4)Mn(CO)(3)](2)(NCMe)(2)(OH2)(2)([mu-eta(2)-(OOCC5H4)Mn(CO)(3)](2)){Mn[mu-(OOCC5H4)Mn(CO)(3)](4)[mu-eta(2)-(OOCC5H4)Mn(CO)(3)](2)(OH2)(2)}(n). The obtained polymer was characterized by X-ray diffraction analysis.
引用
收藏
页码:1092 / 1096
页数:5
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