Formation of 1-D Polymer in Recrystallization of the Adduct Mn[(OOCC5H4)Mn(CO)3]2[O(H)Me]4 from Acetonitrile

被引：0

作者：

Grineva, A. A. ^{[1
]}

Ageshina, A. A. ^{[1
]}

Uvarova, M. A. ^{[1
]}

Nefedov, S. E. ^{[1
]}

机构：

[1] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Leninskii Pr 65, Moscow 119991, Russia

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2016年 / 61卷 / 09期

基金：

俄罗斯基础研究基金会;

关键词：

SINGLE-MOLECULE MAGNETS; MANGANESE(II); METHANOL; DESIGN;

D O I：

10.1134/S0036023616090060

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

It was found that the recrystallization of the adduct Mn[(OOCC5H4)Mn(CO)(3)](2)[O(H)Me](4) from hot acetonitrile in the presence of benzene produces polymer {Mn[mu-(OOCC5H4)Mn(CO)(3)](4)[mu-eta(2)-(OOCC5H4)Mn(CO)(3)](2)(NCMe)(2)(OH2)(2)([mu-eta(2)-(OOCC5H4)Mn(CO)(3)](2)){Mn[mu-(OOCC5H4)Mn(CO)(3)](4)[mu-eta(2)-(OOCC5H4)Mn(CO)(3)](2)(OH2)(2)}(n). The obtained polymer was characterized by X-ray diffraction analysis.

引用

页码：1092 / 1096

页数：5

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