Formation of 1-D Polymer in Recrystallization of the Adduct Mn[(OOCC5H4)Mn(CO)3]2[O(H)Me]4 from Acetonitrile

被引：0
|
作者：
Grineva, A. A. [1 ]
Ageshina, A. A. [1 ]
Uvarova, M. A. [1 ]
Nefedov, S. E. [1 ]
机构：
[1] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Leninskii Pr 65, Moscow 119991, Russia
来源：
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2016年 / 61卷 / 09期
基金：
俄罗斯基础研究基金会;
关键词：
SINGLE-MOLECULE MAGNETS; MANGANESE(II); METHANOL; DESIGN;
D O I：
10.1134/S0036023616090060
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
It was found that the recrystallization of the adduct Mn[(OOCC5H4)Mn(CO)(3)](2)[O(H)Me](4) from hot acetonitrile in the presence of benzene produces polymer {Mn[mu-(OOCC5H4)Mn(CO)(3)](4)[mu-eta(2)-(OOCC5H4)Mn(CO)(3)](2)(NCMe)(2)(OH2)(2)([mu-eta(2)-(OOCC5H4)Mn(CO)(3)](2)){Mn[mu-(OOCC5H4)Mn(CO)(3)](4)[mu-eta(2)-(OOCC5H4)Mn(CO)(3)](2)(OH2)(2)}(n). The obtained polymer was characterized by X-ray diffraction analysis.
引用
收藏
页码：1092 / 1096
页数：5
相关论文
共 50 条
  • [21] Reactions of [Mn(CO)(3){eta(5)-C5H4[(eta(5)-C6H6)Mn(CO)(3)]}] and [WMe(CO)(3){eta(5)-C5H4[(eta(5)-C6H6)Mn(CO)(3)]}] with aryllithium reagents
    Li, RH
    Chen, JB
    Yu, Y
    Sun, J
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1997, (02): : 205 - 211
  • [22] [M(OOCC6H4PO3H)(H2O)] (M(II) = Mn, Co, Ni): layered metal phosphonates showing variable magnetic behavior
    Li, Jin-Tang
    Keene, Tony D.
    Cao, Deng-Ke
    Decurtins, Silvio
    Zheng, Li-Min
    CRYSTENGCOMM, 2009, 11 (07): : 1255 - 1260
  • [23] Reactivity of the bridged borylene complex [μ-BCl{η5-C5H4Me)Mn(CO)2}2]
    Braunschweig, H
    Colling, M
    Hu, CH
    Radacki, K
    INORGANICA CHIMICA ACTA, 2004, 357 (06) : 1822 - 1828
  • [24] KINETICS OF FORMATION OF MNSO4 FROM MNO2 MN2O3 AND MN3O4 AND ITS DECOMPOSITION TO MN2O3 OR MN3O4
    INGRAHAM, TR
    MARIER, P
    TRANSACTIONS OF THE METALLURGICAL SOCIETY OF AIME, 1968, 242 (10): : 2039 - &
  • [25] PHASE-EQUILIBRIA IN THE MN2O3-MN3O4-MNO SYSTEM IN CO2-H2 MIXTURES
    TERAYAMA, K
    IKEDA, M
    TANIGUCHI, M
    TRANSACTIONS OF THE JAPAN INSTITUTE OF METALS, 1983, 24 (01): : 24 - 28
  • [26] KINETICS OF FORMATION OF MNSO4 FROM MNO2 MN2O3 AND MN3O4 AND ITS DECOMPOSITION TO MN2O3 OR MN3O4
    INGRAHAM, TR
    MARIER, P
    JOURNAL OF METALS, 1968, 20 (01): : A178 - &
  • [27] Thermal transformations of Mn5H2(PO4)4•4H2O crystals
    Galkova, TN
    Samuskevich, VV
    ZHURNAL NEORGANICHESKOI KHIMII, 1998, 43 (08): : 1264 - 1269
  • [28] Chelated alkyl halide manganese complexes (η5:η1-C5H4CH2CH2X)Mn(CO)2 from photolysis of (η5-C5H4CH2CH2X)Mn(CO)3
    Casey, CP
    Czerwinski, CJ
    Fraley, ME
    INORGANICA CHIMICA ACTA, 1998, 280 (1-2) : 316 - 321
  • [29] Formation of Mn3O4 nanoparticles from the cluster [Mn12O12(C2H5COO)16(H2O)3] anchored to hybrid mesoporous silica
    Folch, B
    Larionova, J
    Guari, Y
    Guérin, C
    Mehdi, A
    Reyé, C
    JOURNAL OF MATERIALS CHEMISTRY, 2004, 14 (17) : 2703 - 2711
  • [30] The synthesis and structure of a novel alternating 1-D cobalt coordination polymer [Co(2,5-PDC)2(H2O)2Co(H2O)4]·4H2O
    Chengzhi Xie
    Baofeng Zhang
    Xiaoqing Wang
    Ruji Wang
    Guangqiu Shen
    Dezhong Shen
    Journal of Chemical Crystallography, 2007, 37 : 25 - 29
12345