Novel reactivity of unconjugated diimines with [PtCl2(coe)]2 (coe=cis-cyclooctene)

被引：2
|
作者：
Derrah, EJ
Zhang, HW
Nikolcheva, LG
Vogels, CM
Decken, A
Westcott, SA [1 ]
机构：
[1] Mt Allison Univ, Dept Chem, Sackville, NB E4L 1G8, Canada
[2] Univ New Brunswick, Dept Chem, Fredericton, NB E3B 5A3, Canada
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2003年 / 6卷 / 08期
关键词：
unconjugated diimines; platinum; boronate esters; aminoboron;
D O I：
10.1016/S1387-7003(03)00193-X
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The addition of unconjugated diimines [ArC(H)=NCH2CH2N=C(H)Ar, L1: Ar = 3-C(6)H(4)Bpin (pin = 1,2-O2C2Me4), L2: Ar = 4-C(6)H(4)Bpin, and L3: Ar = 4-C6H4OMe] to [PtCl2(coe)](2) (coe = cis-cyclooctene) affords the corresponding dinuclear species [trans-PtCl2(coe)](2)L (1-3), where the diimine coordinates in a monodentate fashion to each of the metal centres. Compounds have been characterized by multinuclear NMR spectroscopy, FT-IR spectroscopy, elemental analyses, and for the case of 2, by X-ray diffraction. (C) 2003 Elsevier Science B.V. All rights reserved.
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页码：1086 / 1090
页数：5
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