Novel reactivity of unconjugated diimines with [PtCl2(coe)]2 (coe=cis-cyclooctene)

被引：2

作者：

Derrah, EJ

Zhang, HW

Nikolcheva, LG

Vogels, CM

Decken, A

Westcott, SA ^{[1
]}

机构：

[1] Mt Allison Univ, Dept Chem, Sackville, NB E4L 1G8, Canada

[2] Univ New Brunswick, Dept Chem, Fredericton, NB E3B 5A3, Canada

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2003年 / 6卷 / 08期

关键词：

unconjugated diimines; platinum; boronate esters; aminoboron;

D O I：

10.1016/S1387-7003(03)00193-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The addition of unconjugated diimines [ArC(H)=NCH2CH2N=C(H)Ar, L1: Ar = 3-C(6)H(4)Bpin (pin = 1,2-O2C2Me4), L2: Ar = 4-C(6)H(4)Bpin, and L3: Ar = 4-C6H4OMe] to [PtCl2(coe)](2) (coe = cis-cyclooctene) affords the corresponding dinuclear species [trans-PtCl2(coe)](2)L (1-3), where the diimine coordinates in a monodentate fashion to each of the metal centres. Compounds have been characterized by multinuclear NMR spectroscopy, FT-IR spectroscopy, elemental analyses, and for the case of 2, by X-ray diffraction. (C) 2003 Elsevier Science B.V. All rights reserved.

引用

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页码：1086 / 1090

页数：5

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