Facile alternative route to cis-[PtCl2(PTA)2] and [PtCl(PTA)3]Cl (PTA=1,3,5-triaza-7-phosphaadamantane)

被引：5

作者：

Demakova, Marina Ya. ^{[1
]}

Luzyanin, Konstantin V. ^{[1
]}

Starova, Galina L. ^{[1
]}

Kukushkin, Vadim Yu. ^{[1
,2
]}

机构：

[1] St Petersburg State Univ, Inst Chem, St Petersburg 198504, Russia

[2] Russian Acad Sci, Inst Macromol Cpds, St Petersburg 199004, Russia

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2014年 / 50卷

关键词：

Platinum(II) complexes; 1,3,5-Triaza-7-phosphaadamantane; Ligand substitution; 1,3,5-TRIAZA-7-PHOSPHAADAMANTANE PTA COMPLEXES; INTRAMOLECULAR HYDROAMINATION; ANTIPROLIFERATIVE ACTIVITY; COORDINATION CHEMISTRY; MOLECULAR-STRUCTURE; SPECTRAL PROPERTIES; AQUEOUS-SOLUTION; METAL-COMPLEXES; WATER; DERIVATIVES;

D O I：

10.1016/j.inoche.2014.10.002

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of trans-[PtCl2(Me2SO)(2)] with 2 equivs of 1,3,5-triaza-7-phosphaadamantane (PTA) in MeNO2 at RT furnished cis-[PtCl2(PTA)(2)] (1) in 87% isolated yield. Corresponding reaction of K-2[PtCl4] with 1 equiv, of PTA in aqueous EtOH at RT led to [PtCl(PTA)(3)]Cl (2) in 84% isolated yield. Complexes 1 and 2 were characterized by elemental analyses (C, H, N), HR-ESI+/--MS, IR, H-1 and P-31{H-1} NMR spectroscopic techniques, and by single-crystal X-ray diffraction for 1. (C) 2014 Elsevier B.V. All rights reserved.

引用

页码：17 / 18

页数：2

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