Regio- and stereoselective synthesis of (Z)-vinylgermanes by hydrogermylation of alkynes

被引：0

作者：

David-Quillot, Frank ^{[1
]}

Thiery, Valerie ^{[2
]}

Abarbri, Mohamed ^{[1
]}

Thibonnet, Jerome ^{[1
]}

Besson, Thierry ^{[2
]}

Duchene, Alain ^{[1
]}

机构：

[1] Fac Sci Tours, Lab Synth & Physicochim Organ & Therapeut, F-37200 Tours, France

[2] Univ La Rochelle, CNRS, UFR Sci Fondamentales & Sci Ingn, Lab Biotechnol & Chim Bioorgan,FRE 2766, F-17042 La Rochelle 1, France

来源：

MAIN GROUP METAL CHEMISTRY | 2007年 / 30卷 / 05期

关键词：

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We have developed a new method for hydrogermylation of alkynes in alkenylgermanes. These reactions took place readily in THF under ultrasound or microwave conditions, leading to vinylgermanes with good regioselectivity and high stereoselectivity without transition metal catalysts. We demonstrated that the use of AIBN is not necessary under ultrasound or microwave conditions, and (Z)-alkenylgermane was the major product in all cases.

引用

页码：235 / 244

页数：10

共 50 条

[21] Regio- and stereoselective enyne cross metathesis of silylated internal alkynes
Kim, M
Park, S
Maifeld, SV
Lee, D
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (33) : 10242 - 10243
[22] Highly Regio- and Stereoselective Intermolecular Seleno- and Thioamination of Alkynes
Zheng, Guangfan
Zhao, Jinbo
Li, Zhanyu
Zhang, Qiao
Sun, Jiaqiong
Sun, Haizhu
Zhang, Qian
[J]. CHEMISTRY-A EUROPEAN JOURNAL, 2016, 22 (10) : 3513 - 3518
[23] Regio- and Stereoselective Synthesis of Benzo--sultams by Palladium-Catalyzed Hydrocarbonation of Alkynes
Debnath, Sudarshan
Mondal, Shovan
[J]. SYNTHESIS-STUTTGART, 2016, 48 (05): : 710 - 722
[24] Copper Promoted Regio- and Stereoselective Aminochlorination of Alkynes and Alkenes with NFSI
Wang, Weilin
Liu, Lingyan
Chang, Weixing
Li, Jing
[J]. CHEMISTRY-A EUROPEAN JOURNAL, 2018, 24 (34) : 8542 - 8547
[25] Regio- and stereoselective addition of sterically hindered silylboranes to terminal alkynes
Da Silva, JCA
Birot, M
Pillot, JP
Pétraud, M
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2002, 646 (1-2) : 179 - 190
[26] Highly regio- and stereoselective synthesis of tetrasubstituted cyclobutenes via cyclodimerization of alkynes mediated by zirconium
Liu, YH
Liu, MN
Song, ZQ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (11) : 3662 - 3663
[27] A novel regio- and stereoselective synthesis of isoindolines
Kukkola, PJ
Bilci, NA
Ikeler, TJ
[J]. TETRAHEDRON LETTERS, 1996, 37 (29) : 5065 - 5068
[28] Regio- and stereoselective synthesis of vinyl sulfides via PhSeBr-catalyzed hydrothiolation of alkynes
Manarin, Flavia
Roehrs, Juliano A.
Prigol, Marina
Alves, Diego
Nogueira, Cristina W.
Zeni, Gilson
[J]. TETRAHEDRON LETTERS, 2007, 48 (28) : 4805 - 4808
[29] Regio- and stereoselective synthesis of alkenylphosphines: A rhodium-catalyzed hydrophosphination of alkynes using a silylphosphine
Hayashi, Minoru
Matsuura, Yutaka
Watanabe, Yutaka
[J]. JOURNAL OF ORGANIC CHEMISTRY, 2006, 71 (24): : 9248 - 9251
[30] Regio- and stereoselective oxidative conversion of alkynes to sulfenylated α,β-unsaturated carbonyls
Tang, Meizhong
Wang, Ye-Xin
Huang, Shenlin
Xie, Lan-Gui
[J]. ORGANIC CHEMISTRY FRONTIERS, 2023, 10 (10): : 2416 - 2421

← 1 2 3 4 5 →