A new hexanuclear rhenium cluster complex with six terminal acetate ligands: Synthesis, structure, and properties of K4[Re6S8(CH3COO)6]•8H2O

被引：34
|
作者：
Brylev, Konstantin A. [1 ]
Mironov, Yuri V. [1 ]
Fedorov, Vladimir E. [1 ]
Kim, Sung-Jin [2 ]
Pietzsch, Hans-Juergen [3 ]
Stephan, Holger [3 ]
Ito, Akitaka [4 ]
Kitamura, Noboru [4 ]
机构：
[1] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk 630090, Russia
[2] Ewha Womans Univ, Dept Chem & Nano Sci, Seoul 120750, South Korea
[3] Forschungszentrum Dresden Rossendorf, Inst Radiopharm, D-01314 Dresden, Germany
[4] Hokkaido Univ, Dept Chem, Grad Sch Sci, Sapporo, Hokkaido 0600810, Japan
来源：
INORGANICA CHIMICA ACTA | 2010年 / 363卷 / 11期
基金：
日本学术振兴会; 俄罗斯基础研究基金会;
关键词：
Synthesis; Cluster compounds; Rhenium; Carboxylate ligands; Luminescence; CRYSTAL-STRUCTURE; HEXARHENIUM(III) CLUSTERS; ACETIC-ACID; ORGANIC-LIGANDS; CORE; SE; MOLYBDENUM; SUBSTITUTION; LUMINESCENT; TEMPERATURE;
D O I：
10.1016/j.ica.2010.04.042
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A room-temperature reaction between [Re6S8(OH)(6)](4) and acetic acid in an aqueous solution resulted in the substitution of all terminal hydroxo groups by acetate ligands, affording a new hexanuclear anionic rhenium cluster complex [Re6S8(CH3COO)(6)](4). The complex was isolated as a potassium salt with the composition of K-4[Re6S8(CH3COO)(6)]center dot 8H(2)O (1) and characterized by X-ray single- crystal diffraction and elemental analyses, IR, H-1 NMR, UV-Vis, and luminescence spectroscopies. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码：2686 / 2691
页数：6
相关论文
共 50 条
  • [41] Crystal structure of the octahedral cluster complex trans-[{Re6S8}(pyz)4I2]·2pyz
    M. A. Shestopalov
    A. A. Ivanov
    A. I. Smolentsev
    Yu. V. Mironov
    Journal of Structural Chemistry, 2014, 55 : 139 - 141
  • [42] Structure of a new molecular rhenium cluster complex: trans-{[Ni(NH3)5]2×[Re6Se8(CN)4(OH)2]}·6H2O
    A. V. Ermolaev
    A. I. Smolentsev
    Yu. V. Mironov
    Journal of Structural Chemistry, 2011, 52 : 1124 - 1126
  • [43] INTERACTION OF NEUTRAL AND ANIONIC O-DONOR ORGANIC-LIGANDS WITH EUROPIUM(III) IN THE MACROCYCLIC COMPLEX [EU(CH3COO)2(C22H26N6)]CL4H2O AND CRYSTAL-STRUCTURE OF [EU(CH3COO)2(C22H26N6)](CH3COO)9H2O
    FONDA, KK
    SMAILES, DL
    VALLARINO, LM
    BOMBIERI, G
    BENETOLLO, F
    POLO, A
    DECOLA, L
    POLYHEDRON, 1993, 12 (05) : 549 - 562
  • [44] ANHYDROUS LANTHANUM ACETATE, LA(CH3COO)3, AND ITS PRECURSOR, (NH4)3[LA(CH3COO)6].1/2H2O - SYNTHESIS, STRUCTURES, THERMAL-BEHAVIOR
    MEYER, G
    GIESKEVOLLMER, D
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1993, 619 (09): : 1603 - 1608
  • [45] Synthesis and Crystal Structure of the Azide K4[Re6Se8i(N3)6a]•4H2O; Luminescence, Redox, and DFT Investigations of the [Re6Se8i(N3)6a]4- Cluster Unit
    Gandubert, Aurore
    Brylev, Konstantin A.
    Thi Thuong Nguyen
    Naumov, Nikolai G.
    Kitamura, Noboru
    Molard, Yann
    Gautier, Regis
    Cordier, Stephane
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2013, 639 (10): : 1756 - 1762
  • [46] First example of bidentate coordination of the octahedral rhenium(III) cluster anion to a 3d-transition metal ion: Assembly of 2D coordination network [{Cu(NH3)3}2{Re6S8(OH)4(μ-OH)2}]•8H2O
    Smolentsev, Anton I.
    Mironov, Yuri V.
    POLYHEDRON, 2013, 50 (01) : 490 - 494
  • [47] Novel inorganic ionic compounds based on Re6 chalcocyanide cluster complexes:: synthesis and crystal structures of [CuNH3(trien)]2[Re6S8(CN)6]•7H2O, [CuNH3(trien)]2[Re6Se8(CN)6] and [CuNH3(trien)]2[Re6Te8(CN)6]•H2O
    Brylev, KA
    Naumov, NG
    Peris, G
    Llusar, R
    Fedorov, VE
    POLYHEDRON, 2003, 22 (25-26) : 3383 - 3387
  • [48] Synthesis and structure of K2[HMo6(VI)V(V)O22(NH3CH2COO)3]•8H2O:: a new example of a polyoxomolybdovanadate coordinated by a glycinato ligand
    Cindric, M
    Strukan, N
    Devcic, M
    Kamenar, B
    INORGANIC CHEMISTRY COMMUNICATIONS, 1999, 2 (11) : 558 - 560
  • [49] Hydrothermal Synthesis,Crystal Structure and Electrochemical Properties of a New Dinuclear Copper Complex [C2H6ON]2[Cu2Cl2(μ-CH3COO)4]
    许瑞波
    许兴友
    王明艳
    杨绪杰
    汪信
    陆路德
    马卫兴
    Chinese Journal of Structural Chemistry, 2009, 28 (06) : 703 - 707
  • [50] Crystal Structures and Properties of [M(NH3)5Cl]2[Re6S8(CN)6]•3H2O
    Yusenko, Kirill
    Shusharina, Elena
    Baidina, Iraida
    Gromilov, Sergey
    ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2007, 63 : S158 - S159
12345