A new hexanuclear rhenium cluster complex with six terminal acetate ligands: Synthesis, structure, and properties of K4[Re6S8(CH3COO)6]•8H2O

被引：34

作者：

Brylev, Konstantin A. ^{[1
]}

Mironov, Yuri V. ^{[1
]}

Fedorov, Vladimir E. ^{[1
]}

Kim, Sung-Jin ^{[2
]}

Pietzsch, Hans-Juergen ^{[3
]}

Stephan, Holger ^{[3
]}

Ito, Akitaka ^{[4
]}

Kitamura, Noboru ^{[4
]}

机构：

[1] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk 630090, Russia

[2] Ewha Womans Univ, Dept Chem & Nano Sci, Seoul 120750, South Korea

[3] Forschungszentrum Dresden Rossendorf, Inst Radiopharm, D-01314 Dresden, Germany

[4] Hokkaido Univ, Dept Chem, Grad Sch Sci, Sapporo, Hokkaido 0600810, Japan

来源：

INORGANICA CHIMICA ACTA | 2010年 / 363卷 / 11期

基金：

日本学术振兴会; 俄罗斯基础研究基金会;

关键词：

Synthesis; Cluster compounds; Rhenium; Carboxylate ligands; Luminescence; CRYSTAL-STRUCTURE; HEXARHENIUM(III) CLUSTERS; ACETIC-ACID; ORGANIC-LIGANDS; CORE; SE; MOLYBDENUM; SUBSTITUTION; LUMINESCENT; TEMPERATURE;

D O I：

10.1016/j.ica.2010.04.042

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A room-temperature reaction between [Re6S8(OH)(6)](4) and acetic acid in an aqueous solution resulted in the substitution of all terminal hydroxo groups by acetate ligands, affording a new hexanuclear anionic rhenium cluster complex [Re6S8(CH3COO)(6)](4). The complex was isolated as a potassium salt with the composition of K-4[Re6S8(CH3COO)(6)]center dot 8H(2)O (1) and characterized by X-ray single- crystal diffraction and elemental analyses, IR, H-1 NMR, UV-Vis, and luminescence spectroscopies. (C) 2010 Elsevier B.V. All rights reserved.

引用

页码：2686 / 2691

页数：6

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