Solvent-free synthesis of metal phosphate-oxalates with layered and zeolitic structures

被引：4
|
作者：
Luan, Lindong [1 ]
Zou, Guohong [2 ]
Lin, Zhien [2 ]
Cai, Huaqiang [1 ]
Huang, Hui [1 ]
机构：
[1] China Acad Engn Phys, Inst Chem Mat, Mianyang 621900, Peoples R China
[2] Sichuan Univ, Coll Chem, Chengdu 610064, Sichuan, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2018年 / 96卷
基金：
中国国家自然科学基金;
关键词：
Solvent-free synthesis; Metal phosphate-oxalate; Zeolitic topology; Magnetism; Photoluminescence; SULFATE-OXALATES; BIMODAL POROSITY; ZINC PHOSPHATE; LIGHT PHOSPHOR; FRAMEWORK; TOPOLOGIES; CLUSTER; IONS; UNIT;
D O I：
10.1016/j.inoche.2018.08.003
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Three new metal phosphate-oxalates, namely, (H(2)dmp)(0.5)center dot Mn(H2PO4)(C2O4) (1), and H2R center dot In-2(HPO4)(2)(H2PO4)(2)(C2O4)center dot H2O (R = dmp (2) and dmapa (3)) were prepared under solvent-free conditions, where dmp = 1,4-dimethylpiperazine and dmapa = 3-(dimethylamino)-1-propylamine. Compound 1 has a layered structure with an sql net. Compounds 2 and 3 are isostructural and have large 16-ring channels with a zeolitic crb net. The temperature dependence of the magnetic susceptibility of compound 1 and the photoluminescent property of compound 3 were investigated.
引用
收藏
页码：65 / 68
页数：4
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