Isonicotinic acid-templated metal phosphate-oxalates: solvent-free synthesis, luminescence, and proton conduction

被引：7
|
作者：
Huang, Lijuan [1 ,2 ]
Xu, Haiping [1 ]
Zhao, Yan [2 ]
Huang, Ling [2 ]
Bi, Jian [2 ]
Zeng, Hongmei [1 ]
Zou, Guohong [1 ]
Gao, Daojiang [2 ]
Lin, Zhien [1 ]
机构：
[1] Sichuan Univ, Coll Chem, Chengdu 610064, Peoples R China
[2] Sichuan Normal Univ, Coll Chem & Mat Sci, Chengdu 610068, Peoples R China
来源：
CRYSTENGCOMM | 2021年 / 23卷 / 39期
基金：
中国国家自然科学基金;
关键词：
HONEYCOMB STRUCTURE; ORGANIC FRAMEWORKS; OXALATOPHOSPHATES;
D O I：
10.1039/d1ce00873k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Two new metal phosphate-oxalates (denoted SCU-26 and SCU-27) were prepared under solvent-free conditions using isonicotinic acid as a structure-directing agent. SCU-26 has a neutral layered structure showing intense blue-green luminescence with a high quantum yield of 28.35%. SCU-27 has an anionic layered structure with a high proton conductivity of 9.0 x 10(-4) S cm(-1) at 85 degrees C under 95% relative humidity.
引用
收藏
页码：6855 / 6858
页数：4
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