Solvent-free synthesis of new metal phosphate-oxalates with helical-chain and slablike structures

被引：9
|
作者：
Wang, Wei [1 ]
Luan, Lindong [2 ]
Yang, Meng [1 ]
Wang, Kangcai [3 ]
Lin, Zhien [1 ]
机构：
[1] Sichuan Univ, Coll Chem, Chengdu 610064, Peoples R China
[2] Beijing Inst Technol, Sch Chem, Beijing 100081, Peoples R China
[3] China Acad Engn Phys, Inst Chem Mat, Mianyang 621900, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2017年 / 75卷
基金：
中国博士后科学基金;
关键词：
Solvent-free synthesis; Inorganic-organic hybrid solids; Phosphate; Oxalate; Proton conductivity; ORGANIC FRAMEWORKS; CLUSTER; TOPOLOGY;
D O I：
10.1016/j.inoche.2016.12.002
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two metal phosphate-oxalate, namely, H(3)pmdeta center dot Ga-2(HPO4)(H2PO4)(C2O4)(3) (1) and HzInPiP " Mn2(H2PO4)2(C204)24120 (2), were prepared under solvent-free conditions, where pmdeta = N',N '',N ''-pentamethyldiethylenetriamine and mpip = 1-methylpiperzaine. Compound 1 features a helical-chain structure containing cyclic inorganic building block. Compound 2 has a slablike structure with a kgd net. The magnetic and proton-conducting properties of compound 2 were also investigated. (C) 2016 Published by Elsevier B.V.
引用
收藏
页码：46 / 48
页数：3
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